(S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate

In the title compound, C(11)H(15)N(3) (2+)·2Cl(−)·H(2)O, one N atom of the imidazole ring and the N atom of the pyrrolidine ring are protonated. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring benzimidazole systems [centroid–centroid duista...

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Detalles Bibliográficos
Autor principal: Jing, Dai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969638/
https://www.ncbi.nlm.nih.gov/pubmed/21583238
http://dx.doi.org/10.1107/S1600536809019084
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author Jing, Dai
author_facet Jing, Dai
author_sort Jing, Dai
collection PubMed
description In the title compound, C(11)H(15)N(3) (2+)·2Cl(−)·H(2)O, one N atom of the imidazole ring and the N atom of the pyrrolidine ring are protonated. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring benzimidazole systems [centroid–centroid duistance = 3.712 (2) Å]. The crystal structure is further stabilized by inter­molecular N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds.
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spelling pubmed-29696382010-12-30 (S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate Jing, Dai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(15)N(3) (2+)·2Cl(−)·H(2)O, one N atom of the imidazole ring and the N atom of the pyrrolidine ring are protonated. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring benzimidazole systems [centroid–centroid duistance = 3.712 (2) Å]. The crystal structure is further stabilized by inter­molecular N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969638/ /pubmed/21583238 http://dx.doi.org/10.1107/S1600536809019084 Text en © Dai Jing 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jing, Dai
(S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate
title (S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate
title_full (S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate
title_fullStr (S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate
title_full_unstemmed (S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate
title_short (S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate
title_sort (s)-2-(2-pyrrolidinio)-1h-benzimidazol-3-ium dichloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969638/
https://www.ncbi.nlm.nih.gov/pubmed/21583238
http://dx.doi.org/10.1107/S1600536809019084
work_keys_str_mv AT jingdai s22pyrrolidinio1hbenzimidazol3iumdichloridemonohydrate

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