Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate

In the title mononuclear complex, [Co(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Co(II) atom exhibits a distorted octa­hedral geometry involving an N atom of a 1H-benzimidazole-5,6-dicarboxyl­ate ligand and five water O atoms. A supra­molecular network is generated through inter­molecular O—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Wang, Hao, Li, Shi-Jie, Qin, Pei-Wen, Hu, Shi-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969642/
https://www.ncbi.nlm.nih.gov/pubmed/21583056
http://dx.doi.org/10.1107/S1600536809019904
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author Song, Wen-Dong
Wang, Hao
Li, Shi-Jie
Qin, Pei-Wen
Hu, Shi-Wei
author_facet Song, Wen-Dong
Wang, Hao
Li, Shi-Jie
Qin, Pei-Wen
Hu, Shi-Wei
author_sort Song, Wen-Dong
collection PubMed
description In the title mononuclear complex, [Co(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Co(II) atom exhibits a distorted octa­hedral geometry involving an N atom of a 1H-benzimidazole-5,6-dicarboxyl­ate ligand and five water O atoms. A supra­molecular network is generated through inter­molecular O—H⋯O hydrogen-bonding inter­actions involving the coordinated and uncoordinated water mol­ecules and the carboxyl O atoms of the organic ligand. An inter­molecular N—H⋯O hydrogen bond is also observed.
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spelling pubmed-29696422010-12-30 Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate Song, Wen-Dong Wang, Hao Li, Shi-Jie Qin, Pei-Wen Hu, Shi-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Co(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Co(II) atom exhibits a distorted octa­hedral geometry involving an N atom of a 1H-benzimidazole-5,6-dicarboxyl­ate ligand and five water O atoms. A supra­molecular network is generated through inter­molecular O—H⋯O hydrogen-bonding inter­actions involving the coordinated and uncoordinated water mol­ecules and the carboxyl O atoms of the organic ligand. An inter­molecular N—H⋯O hydrogen bond is also observed. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969642/ /pubmed/21583056 http://dx.doi.org/10.1107/S1600536809019904 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Wang, Hao
Li, Shi-Jie
Qin, Pei-Wen
Hu, Shi-Wei
Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate
title Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate
title_full Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate
title_fullStr Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate
title_full_unstemmed Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate
title_short Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))cobalt(II) penta­hydrate
title_sort penta­aqua­(1h-benzimidazole-5,6-di­carboxyl­ato-κn (3))cobalt(ii) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969642/
https://www.ncbi.nlm.nih.gov/pubmed/21583056
http://dx.doi.org/10.1107/S1600536809019904
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