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Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)

The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964–1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals aniso...

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Detalles Bibliográficos
Autores principales: Okio, Coco K. Y. A., Speziali, Nivaldo L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969649/
https://www.ncbi.nlm.nih.gov/pubmed/21583036
http://dx.doi.org/10.1107/S1600536809018522
Descripción
Sumario:The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964–1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and inter­atomic distances. The complex features a distorted S(6) octa­hedral coordination geometry for tin and a cis disposition of the monodentate dithio­carbamate ligands.