Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)

The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964–1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals aniso...

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Detalles Bibliográficos
Autores principales: Okio, Coco K. Y. A., Speziali, Nivaldo L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969649/
https://www.ncbi.nlm.nih.gov/pubmed/21583036
http://dx.doi.org/10.1107/S1600536809018522
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author Okio, Coco K. Y. A.
Speziali, Nivaldo L.
author_facet Okio, Coco K. Y. A.
Speziali, Nivaldo L.
author_sort Okio, Coco K. Y. A.
collection PubMed
description The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964–1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and inter­atomic distances. The complex features a distorted S(6) octa­hedral coordination geometry for tin and a cis disposition of the monodentate dithio­carbamate ligands.
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spelling pubmed-29696492010-12-30 Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV) Okio, Coco K. Y. A. Speziali, Nivaldo L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964–1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and inter­atomic distances. The complex features a distorted S(6) octa­hedral coordination geometry for tin and a cis disposition of the monodentate dithio­carbamate ligands. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969649/ /pubmed/21583036 http://dx.doi.org/10.1107/S1600536809018522 Text en © Okio and Speziali 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Okio, Coco K. Y. A.
Speziali, Nivaldo L.
Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)
title Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)
title_full Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)
title_fullStr Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)
title_full_unstemmed Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)
title_short Redetermination of tetra­kis(N,N-diethyl­dithio­carbamato)tin(IV)
title_sort redetermination of tetra­kis(n,n-diethyl­dithio­carbamato)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969649/
https://www.ncbi.nlm.nih.gov/pubmed/21583036
http://dx.doi.org/10.1107/S1600536809018522
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