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trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate

In the title centrosymmetric complex, [Zn(C(7)H(5)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is coordinated in a trans mode by two symmetry-related bis-chelating 6-methoxycarbonyl­pyridazine-3-carboxyl­ate ligands via N and O atoms, and by two aqua ligand O atoms in axial positions, in a slightl...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969658/
https://www.ncbi.nlm.nih.gov/pubmed/21583007
http://dx.doi.org/10.1107/S1600536809017115
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description In the title centrosymmetric complex, [Zn(C(7)H(5)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is coordinated in a trans mode by two symmetry-related bis-chelating 6-methoxycarbonyl­pyridazine-3-carboxyl­ate ligands via N and O atoms, and by two aqua ligand O atoms in axial positions, in a slightly distorted octa­hedral environment. In the crystal structure, complex mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds between coordinated and solvent water mol­ecules and carboxyl­ate O atoms, forming mol­ecular ribbons propagating along the a axis.
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spelling pubmed-29696582010-12-30 trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric complex, [Zn(C(7)H(5)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is coordinated in a trans mode by two symmetry-related bis-chelating 6-methoxycarbonyl­pyridazine-3-carboxyl­ate ligands via N and O atoms, and by two aqua ligand O atoms in axial positions, in a slightly distorted octa­hedral environment. In the crystal structure, complex mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds between coordinated and solvent water mol­ecules and carboxyl­ate O atoms, forming mol­ecular ribbons propagating along the a axis. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969658/ /pubmed/21583007 http://dx.doi.org/10.1107/S1600536809017115 Text en © Starosta and Leciejewicz 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate
title trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate
title_full trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate
title_fullStr trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate
title_full_unstemmed trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate
title_short trans-Diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) N,O)zinc(II) dihydrate
title_sort trans-diaqua­bis(6-methoxycarbonyl­pyridazine-3-carboxyl­ato-κ(2) n,o)zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969658/
https://www.ncbi.nlm.nih.gov/pubmed/21583007
http://dx.doi.org/10.1107/S1600536809017115
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