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2,2′-Dimethoxy-4,4′-[rel-(2R,3S)-2,3-dimethylbutane-1,4-diyl]diphenol
The title molecule, C(20)H(26)O(4), commonly known as meso-dihydroguaiaretic acid, is a naturally occurring lignan extracted from Larrea tridentata and other plants. The molecule has a noncrystallographic inversion center situated at the midpoint of the central C—C bond, generating the meso stere...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969660/ https://www.ncbi.nlm.nih.gov/pubmed/21583141 http://dx.doi.org/10.1107/S1600536809017292 |
Sumario: | The title molecule, C(20)H(26)O(4), commonly known as meso-dihydroguaiaretic acid, is a naturally occurring lignan extracted from Larrea tridentata and other plants. The molecule has a noncrystallographic inversion center situated at the midpoint of the central C—C bond, generating the meso stereoisomer. The central C—C—C—C alkyl chain displays an all-trans conformation, allowing an almost parallel arrangement of the benzene rings, which make a dihedral angle of 5.0 (3)°. Both hydroxy groups form weak O—H⋯O—H chains of hydrogen bonds along [100]. The resulting supramolecular structure is an undulating plane parallel to (010). |
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