2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one

The title compound, C(20)H(19)Br(2)NO, shows a chair–chair conformation for the aza­bicycle with an equatorial disposition of the 4-bromo­phenyl groups [dihedral angle between the aromatic rings = 16.48 (3)°]. In the crystal, a short Br⋯Br contact [3.520 (4) Å] occurs and the structure is further st...

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Detalles Bibliográficos
Autores principales: Parthiban, P., Ramkumar, V., Amirthaganesan, S., Jeong, Yeon Tae
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969662/
https://www.ncbi.nlm.nih.gov/pubmed/21583207
http://dx.doi.org/10.1107/S1600536809017565
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author Parthiban, P.
Ramkumar, V.
Amirthaganesan, S.
Jeong, Yeon Tae
author_facet Parthiban, P.
Ramkumar, V.
Amirthaganesan, S.
Jeong, Yeon Tae
author_sort Parthiban, P.
collection PubMed
description The title compound, C(20)H(19)Br(2)NO, shows a chair–chair conformation for the aza­bicycle with an equatorial disposition of the 4-bromo­phenyl groups [dihedral angle between the aromatic rings = 16.48 (3)°]. In the crystal, a short Br⋯Br contact [3.520 (4) Å] occurs and the structure is further stabilized by N—H⋯O hydrogen bonds and C—H⋯O inter­actions.
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spelling pubmed-29696622010-12-30 2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one Parthiban, P. Ramkumar, V. Amirthaganesan, S. Jeong, Yeon Tae Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(19)Br(2)NO, shows a chair–chair conformation for the aza­bicycle with an equatorial disposition of the 4-bromo­phenyl groups [dihedral angle between the aromatic rings = 16.48 (3)°]. In the crystal, a short Br⋯Br contact [3.520 (4) Å] occurs and the structure is further stabilized by N—H⋯O hydrogen bonds and C—H⋯O inter­actions. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969662/ /pubmed/21583207 http://dx.doi.org/10.1107/S1600536809017565 Text en © Parthiban et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Parthiban, P.
Ramkumar, V.
Amirthaganesan, S.
Jeong, Yeon Tae
2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title 2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full 2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_short 2,4-Bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
title_sort 2,4-bis(4-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969662/
https://www.ncbi.nlm.nih.gov/pubmed/21583207
http://dx.doi.org/10.1107/S1600536809017565
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