catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]

In the title complex, [Ag(NO(3))(C(5)H(5)NO)](n), the Ag(I) atom is coordinated by two O atoms from two different 4-pyridone ligands and two O atoms from one nitrate anion, displaying a nearly planar coordination geometry. The O atoms of two 4-pyridone ligands bridge two symmetrically related AgNO(3...

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Detalles Bibliográficos
Autores principales: Wu, Xian-Ge, Xiao, Jun-Xia, Qin, Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969665/
https://www.ncbi.nlm.nih.gov/pubmed/21583044
http://dx.doi.org/10.1107/S1600536809019138
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author Wu, Xian-Ge
Xiao, Jun-Xia
Qin, Liang
author_facet Wu, Xian-Ge
Xiao, Jun-Xia
Qin, Liang
author_sort Wu, Xian-Ge
collection PubMed
description In the title complex, [Ag(NO(3))(C(5)H(5)NO)](n), the Ag(I) atom is coordinated by two O atoms from two different 4-pyridone ligands and two O atoms from one nitrate anion, displaying a nearly planar coordination geometry. The O atoms of two 4-pyridone ligands bridge two symmetrically related AgNO(3) units, forming a dimer, with an Ag⋯Ag separation of 3.680 (2) Å. Neighbouring dimers are linked into an infinite chain through weak Ag⋯O inter­actions [2.765 (2) Å], Ag⋯Ag inter­actions [3.1511 (4) Å] and π–π stacking inter­actions [centroid–centroid distance = 3.623 (4) Å]. N—H⋯O and C—H⋯O hydrogen bonds assemble these chains into a three-dimensional network.
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spelling pubmed-29696652010-12-30 catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O] Wu, Xian-Ge Xiao, Jun-Xia Qin, Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(NO(3))(C(5)H(5)NO)](n), the Ag(I) atom is coordinated by two O atoms from two different 4-pyridone ligands and two O atoms from one nitrate anion, displaying a nearly planar coordination geometry. The O atoms of two 4-pyridone ligands bridge two symmetrically related AgNO(3) units, forming a dimer, with an Ag⋯Ag separation of 3.680 (2) Å. Neighbouring dimers are linked into an infinite chain through weak Ag⋯O inter­actions [2.765 (2) Å], Ag⋯Ag inter­actions [3.1511 (4) Å] and π–π stacking inter­actions [centroid–centroid distance = 3.623 (4) Å]. N—H⋯O and C—H⋯O hydrogen bonds assemble these chains into a three-dimensional network. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969665/ /pubmed/21583044 http://dx.doi.org/10.1107/S1600536809019138 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Xian-Ge
Xiao, Jun-Xia
Qin, Liang
catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]
title catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]
title_full catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]
title_fullStr catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]
title_full_unstemmed catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]
title_short catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ(3)-4-pyridone-κ(3) O:O:O]
title_sort catena-poly[[(nitrato-κ(2) o,o′)silver(i)]-μ(3)-4-pyridone-κ(3) o:o:o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969665/
https://www.ncbi.nlm.nih.gov/pubmed/21583044
http://dx.doi.org/10.1107/S1600536809019138
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