Tris{2-meth­oxy-6-[(4-methyl­phenyl)­iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)cerium(III)

The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methyl­phenyl)iminometh­yl]­phenol (HL) ligands and three independent thio­cyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Xian, Hui-Duo, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969666/
https://www.ncbi.nlm.nih.gov/pubmed/21583015
http://dx.doi.org/10.1107/S1600536809016808
Descripción
Sumario:The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methyl­phenyl)iminometh­yl]­phenol (HL) ligands and three independent thio­cyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intra­molecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine.

Ejemplares similares