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Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(thiocyanato-κN)cerium(III)
The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands and three independent thiocyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969666/ https://www.ncbi.nlm.nih.gov/pubmed/21583015 http://dx.doi.org/10.1107/S1600536809016808 |
| _version_ | 1782190220146376704 |
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| author | Liu, Jian-Feng Xian, Hui-Duo Zhao, Guo-Liang |
| author_facet | Liu, Jian-Feng Xian, Hui-Duo Zhao, Guo-Liang |
| author_sort | Liu, Jian-Feng |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands and three independent thiocyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine. |
| format | Text |
| id | pubmed-2969666 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29696662010-12-30 Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(thiocyanato-κN)cerium(III) Liu, Jian-Feng Xian, Hui-Duo Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands and three independent thiocyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969666/ /pubmed/21583015 http://dx.doi.org/10.1107/S1600536809016808 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jian-Feng Xian, Hui-Duo Zhao, Guo-Liang Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(thiocyanato-κN)cerium(III) |
| title | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(thiocyanato-κN)cerium(III) |
| title_full | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(thiocyanato-κN)cerium(III) |
| title_fullStr | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(thiocyanato-κN)cerium(III) |
| title_full_unstemmed | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(thiocyanato-κN)cerium(III) |
| title_short | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(thiocyanato-κN)cerium(III) |
| title_sort | tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
o,o′}tris(thiocyanato-κn)cerium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969666/ https://www.ncbi.nlm.nih.gov/pubmed/21583015 http://dx.doi.org/10.1107/S1600536809016808 |
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