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1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate
In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (−), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84 (8)°. The molecular structure exhibits an intramolecular O—H⋯O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cation...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969671/ https://www.ncbi.nlm.nih.gov/pubmed/21583268 http://dx.doi.org/10.1107/S160053680901928X |
Sumario: | In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (−), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84 (8)°. The molecular structure exhibits an intramolecular O—H⋯O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cations and anions are connected via O—H⋯N and O—H⋯F hydrogen bonds, resulting in a trifurcated interaction for the phenolic H atom. |
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