Cargando…
1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate
In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (−), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84 (8)°. The molecular structure exhibits an intramolecular O—H⋯O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cation...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969671/ https://www.ncbi.nlm.nih.gov/pubmed/21583268 http://dx.doi.org/10.1107/S160053680901928X |
_version_ | 1782190222171176960 |
---|---|
author | Li, Bin Li, Yi-Qun Liu, Jie Zheng, Wen-Jie |
author_facet | Li, Bin Li, Yi-Qun Liu, Jie Zheng, Wen-Jie |
author_sort | Li, Bin |
collection | PubMed |
description | In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (−), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84 (8)°. The molecular structure exhibits an intramolecular O—H⋯O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cations and anions are connected via O—H⋯N and O—H⋯F hydrogen bonds, resulting in a trifurcated interaction for the phenolic H atom. |
format | Text |
id | pubmed-2969671 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29696712010-12-30 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate Li, Bin Li, Yi-Qun Liu, Jie Zheng, Wen-Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (−), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84 (8)°. The molecular structure exhibits an intramolecular O—H⋯O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cations and anions are connected via O—H⋯N and O—H⋯F hydrogen bonds, resulting in a trifurcated interaction for the phenolic H atom. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969671/ /pubmed/21583268 http://dx.doi.org/10.1107/S160053680901928X Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Bin Li, Yi-Qun Liu, Jie Zheng, Wen-Jie 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
title | 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
title_full | 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
title_fullStr | 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
title_full_unstemmed | 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
title_short | 1-{2-[(4-Hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
title_sort | 1-{2-[(4-hydroxy-3-methoxybenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969671/ https://www.ncbi.nlm.nih.gov/pubmed/21583268 http://dx.doi.org/10.1107/S160053680901928X |
work_keys_str_mv | AT libin 124hydroxy3methoxybenzylideneaminoethyl3methylimidazoliumhexafluorophosphate AT liyiqun 124hydroxy3methoxybenzylideneaminoethyl3methylimidazoliumhexafluorophosphate AT liujie 124hydroxy3methoxybenzylideneaminoethyl3methylimidazoliumhexafluorophosphate AT zhengwenjie 124hydroxy3methoxybenzylideneaminoethyl3methylimidazoliumhexafluorophosphate |