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Ethyl 2-amino-4-(3-chloro­phen­yl)-5,10-dioxo-5,10-dihydro-4H-benzo[g]chromene-3-carboxyl­ate

The title mol­ecule, C(22)H(16)ClNO(5), was obtained by the reaction of (E)-ethyl 3-(3-chloro­phen­yl)-2-cyano­acrylate and 2-hydroxy­naphthalene-1,4-dione catalysed by triethylamine in ethanol. In the crystal structure, the chlorobenzene ring makes a dihedral angle of 88.63 (4)° with the fused ring...

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Detalles Bibliográficos
Autores principales: Hu, Xiao, Lei, Song, Yao, Chang-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969697/
https://www.ncbi.nlm.nih.gov/pubmed/21583179
http://dx.doi.org/10.1107/S160053680901753X
Descripción
Sumario:The title mol­ecule, C(22)H(16)ClNO(5), was obtained by the reaction of (E)-ethyl 3-(3-chloro­phen­yl)-2-cyano­acrylate and 2-hydroxy­naphthalene-1,4-dione catalysed by triethylamine in ethanol. In the crystal structure, the chlorobenzene ring makes a dihedral angle of 88.63 (4)° with the fused ring system. The six-membered ring formed by an intra­molecular N—H⋯O hydrogen bond is almost planar. The crystal packing is stabilized by N—H⋯O hydrogen bonds.