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Ethyl 2-[(3-chlorophenyl)hydrazono]-3-oxobutanoate
The molecule of the title oxobutanoate derivative, C(12)H(13)ClN(2)O(3), adopts a keto–hydrazo tautomeric form and is roughly planar, the angle between the benzene ring and the mean plane through the hydrazone and aliphatic chain being 1.49 (6)°. This planarity is further aided by the formation of...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969699/ https://www.ncbi.nlm.nih.gov/pubmed/21583177 http://dx.doi.org/10.1107/S160053680901784X |
Sumario: | The molecule of the title oxobutanoate derivative, C(12)H(13)ClN(2)O(3), adopts a keto–hydrazo tautomeric form and is roughly planar, the angle between the benzene ring and the mean plane through the hydrazone and aliphatic chain being 1.49 (6)°. This planarity is further aided by the formation of an intramolecular N—H⋯O hydrogen bond which generates an S(6) ring motif. The aromatic ring and aliphatic chain have a trans configuration with respect to the N—N bond. In the crystal packing, centrosymmetric R (2) (2)(16) dimers are formed through pairs of weak C—H⋯O(3-oxo) interactions. These dimers are linked together through weak C—H⋯O(carboxylate C=O) interactions into ribbons along the b-axis direction. These ribbons are stacked along the a-axis direction. The crystal also exhibits Cl⋯Cl [3.4988 (6) Å] and C⋯O [3.167 (2)–3.335 (2) Å] short contacts. |
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