N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide

The title compound, C(15)H(12)I(2)N(2)O(3), was synthesized by the condensation of equimolar amounts of 3,5-diiodo­salicylaldehyde and 2-methoxy­benzohydrazide in a methanol solution. There are two independent mol­ecules, A and B, in the asymmetric unit. The dihedral angle between the two benzene ri...

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Detalles Bibliográficos
Autores principales: Peng, San-Jun, Zhang, Fen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969706/
https://www.ncbi.nlm.nih.gov/pubmed/21583253
http://dx.doi.org/10.1107/S160053680901914X
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author Peng, San-Jun
Zhang, Fen
author_facet Peng, San-Jun
Zhang, Fen
author_sort Peng, San-Jun
collection PubMed
description The title compound, C(15)H(12)I(2)N(2)O(3), was synthesized by the condensation of equimolar amounts of 3,5-diiodo­salicylaldehyde and 2-methoxy­benzohydrazide in a methanol solution. There are two independent mol­ecules, A and B, in the asymmetric unit. The dihedral angle between the two benzene rings is 30.2 (2)° for mol­ecule A and 21.7 (2)° for mol­ecule B. There are intra­molecular O—H⋯N and N—H⋯O hydrogen bonds in each mol­ecule. The crystal studied was an inversion twin with a 0.59 (3):0.41 (3) domain ratio.
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spelling pubmed-29697062010-12-30 N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide Peng, San-Jun Zhang, Fen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)I(2)N(2)O(3), was synthesized by the condensation of equimolar amounts of 3,5-diiodo­salicylaldehyde and 2-methoxy­benzohydrazide in a methanol solution. There are two independent mol­ecules, A and B, in the asymmetric unit. The dihedral angle between the two benzene rings is 30.2 (2)° for mol­ecule A and 21.7 (2)° for mol­ecule B. There are intra­molecular O—H⋯N and N—H⋯O hydrogen bonds in each mol­ecule. The crystal studied was an inversion twin with a 0.59 (3):0.41 (3) domain ratio. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969706/ /pubmed/21583253 http://dx.doi.org/10.1107/S160053680901914X Text en © Peng and Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Peng, San-Jun
Zhang, Fen
N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
title N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
title_full N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
title_fullStr N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
title_full_unstemmed N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
title_short N′-(2-Hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
title_sort n′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)-2-methoxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969706/
https://www.ncbi.nlm.nih.gov/pubmed/21583253
http://dx.doi.org/10.1107/S160053680901914X
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