2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)

The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2′-(hexane-1,6-di­yl)diisoquinolinium cations and two [ZnCl(4)](2−) complex anions. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. The dihedral angles between the isoquinoline rings of the two c...

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Detalles Bibliográficos
Autores principales: Ma, Pei-Hua, Fan, Zhi-Fang, Zhang, Yun-Qian, Xiao, Xin, Xue, Sai-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969707/
https://www.ncbi.nlm.nih.gov/pubmed/21583019
http://dx.doi.org/10.1107/S1600536809017693
Descripción
Sumario:The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2′-(hexane-1,6-di­yl)diisoquinolinium cations and two [ZnCl(4)](2−) complex anions. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak inter­molecular π–π stacking inter­actions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å.

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