2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)

The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2′-(hexane-1,6-di­yl)diisoquinolinium cations and two [ZnCl(4)](2−) complex anions. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. The dihedral angles between the isoquinoline rings of the two c...

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Detalles Bibliográficos
Autores principales: Ma, Pei-Hua, Fan, Zhi-Fang, Zhang, Yun-Qian, Xiao, Xin, Xue, Sai-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969707/
https://www.ncbi.nlm.nih.gov/pubmed/21583019
http://dx.doi.org/10.1107/S1600536809017693
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author Ma, Pei-Hua
Fan, Zhi-Fang
Zhang, Yun-Qian
Xiao, Xin
Xue, Sai-Feng
author_facet Ma, Pei-Hua
Fan, Zhi-Fang
Zhang, Yun-Qian
Xiao, Xin
Xue, Sai-Feng
author_sort Ma, Pei-Hua
collection PubMed
description The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2′-(hexane-1,6-di­yl)diisoquinolinium cations and two [ZnCl(4)](2−) complex anions. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak inter­molecular π–π stacking inter­actions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å.
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spelling pubmed-29697072010-12-30 2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II) Ma, Pei-Hua Fan, Zhi-Fang Zhang, Yun-Qian Xiao, Xin Xue, Sai-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2′-(hexane-1,6-di­yl)diisoquinolinium cations and two [ZnCl(4)](2−) complex anions. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak inter­molecular π–π stacking inter­actions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969707/ /pubmed/21583019 http://dx.doi.org/10.1107/S1600536809017693 Text en © Ma et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Pei-Hua
Fan, Zhi-Fang
Zhang, Yun-Qian
Xiao, Xin
Xue, Sai-Feng
2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)
title 2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)
title_full 2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)
title_fullStr 2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)
title_full_unstemmed 2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)
title_short 2,2′-(Hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(II)
title_sort 2,2′-(hexane-1,6-di­yl)diisoquinolinium tetra­chloridozincate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969707/
https://www.ncbi.nlm.nih.gov/pubmed/21583019
http://dx.doi.org/10.1107/S1600536809017693
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