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6-(1H-Indol-3-yl)-4-phenyl-2,2′-bipyridine-5-carbonitrile
In the molecule of the title compound, C(25)H(16)N(4), the pyridine rings are oriented at a dihedral angle of 0.92 (3)°, while the dihedral angle between the benzene ring and the adjacent pyridine ring is 56.51 (3)°. In the crystal structure, intermolecular N—H⋯N hydrogen bonds link the molecules...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969709/ https://www.ncbi.nlm.nih.gov/pubmed/21583060 http://dx.doi.org/10.1107/S1600536809016195 |
Sumario: | In the molecule of the title compound, C(25)H(16)N(4), the pyridine rings are oriented at a dihedral angle of 0.92 (3)°, while the dihedral angle between the benzene ring and the adjacent pyridine ring is 56.51 (3)°. In the crystal structure, intermolecular N—H⋯N hydrogen bonds link the molecules into centrosymmetric dimers, forming R (2) (2)(16) ring motifs. π–π contacts between the pyridine ring and the indole ring system and between the pyridine rings [centroid–centroid distances = 3.923 (2) and 3.724 (2) Å] may further stabilize the structure. Two weak C—H⋯π interactions are also present. |
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