6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile

In the mol­ecule of the title compound, C(25)H(16)N(4), the pyridine rings are oriented at a dihedral angle of 0.92 (3)°, while the dihedral angle between the benzene ring and the adjacent pyridine ring is 56.51 (3)°. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules...

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Detalles Bibliográficos
Autores principales: Zhu, Weijun, Xiang, Yan, Zhu, Songlei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969709/
https://www.ncbi.nlm.nih.gov/pubmed/21583060
http://dx.doi.org/10.1107/S1600536809016195
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author Zhu, Weijun
Xiang, Yan
Zhu, Songlei
author_facet Zhu, Weijun
Xiang, Yan
Zhu, Songlei
author_sort Zhu, Weijun
collection PubMed
description In the mol­ecule of the title compound, C(25)H(16)N(4), the pyridine rings are oriented at a dihedral angle of 0.92 (3)°, while the dihedral angle between the benzene ring and the adjacent pyridine ring is 56.51 (3)°. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(16) ring motifs. π–π contacts between the pyridine ring and the indole ring system and between the pyridine rings [centroid–centroid distances = 3.923 (2) and 3.724 (2) Å] may further stabilize the structure. Two weak C—H⋯π inter­actions are also present.
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spelling pubmed-29697092010-12-30 6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile Zhu, Weijun Xiang, Yan Zhu, Songlei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(25)H(16)N(4), the pyridine rings are oriented at a dihedral angle of 0.92 (3)°, while the dihedral angle between the benzene ring and the adjacent pyridine ring is 56.51 (3)°. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(16) ring motifs. π–π contacts between the pyridine ring and the indole ring system and between the pyridine rings [centroid–centroid distances = 3.923 (2) and 3.724 (2) Å] may further stabilize the structure. Two weak C—H⋯π inter­actions are also present. International Union of Crystallography 2009-05-07 /pmc/articles/PMC2969709/ /pubmed/21583060 http://dx.doi.org/10.1107/S1600536809016195 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Weijun
Xiang, Yan
Zhu, Songlei
6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
title 6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
title_full 6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
title_fullStr 6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
title_full_unstemmed 6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
title_short 6-(1H-Indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
title_sort 6-(1h-indol-3-yl)-4-phenyl-2,2′-bi­pyridine-5-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969709/
https://www.ncbi.nlm.nih.gov/pubmed/21583060
http://dx.doi.org/10.1107/S1600536809016195
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AT xiangyan 61hindol3yl4phenyl22bipyridine5carbonitrile
AT zhusonglei 61hindol3yl4phenyl22bipyridine5carbonitrile

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