catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]

The Co(II) ion in the title complex, [Co(SO(4))(C(13)H(8)N(4))(H(2)O)(2)](n), has a slightly distorted octa­hedral coordination environment formed by two O atoms from two symmetry-related bridging sulfate ligands, two N atoms from a bis-chelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand an...

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Detalles Bibliográficos
Autor principal: Yu, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969714/
https://www.ncbi.nlm.nih.gov/pubmed/21582988
http://dx.doi.org/10.1107/S1600536809016419
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author Yu, Jian
author_facet Yu, Jian
author_sort Yu, Jian
collection PubMed
description The Co(II) ion in the title complex, [Co(SO(4))(C(13)H(8)N(4))(H(2)O)(2)](n), has a slightly distorted octa­hedral coordination environment formed by two O atoms from two symmetry-related bridging sulfate ligands, two N atoms from a bis-chelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water mol­ecules. The bridging sulfate ligands connect Co(II) ions to form a one-dimensional chain along the b-axis direction. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the chains into a three-dimensional network.
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spelling pubmed-29697142010-12-30 catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato] Yu, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) ion in the title complex, [Co(SO(4))(C(13)H(8)N(4))(H(2)O)(2)](n), has a slightly distorted octa­hedral coordination environment formed by two O atoms from two symmetry-related bridging sulfate ligands, two N atoms from a bis-chelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water mol­ecules. The bridging sulfate ligands connect Co(II) ions to form a one-dimensional chain along the b-axis direction. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the chains into a three-dimensional network. International Union of Crystallography 2009-05-07 /pmc/articles/PMC2969714/ /pubmed/21582988 http://dx.doi.org/10.1107/S1600536809016419 Text en © Jian Yu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Jian
catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
title catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
title_full catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
title_fullStr catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
title_full_unstemmed catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
title_short catena-Poly[[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
title_sort catena-poly[[diaqua­(1h-imidazo[4,5-f][1,10]phenanthroline)cobalt(ii)]-μ-sulfato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969714/
https://www.ncbi.nlm.nih.gov/pubmed/21582988
http://dx.doi.org/10.1107/S1600536809016419
work_keys_str_mv AT yujian catenapolydiaqua1himidazo45f110phenanthrolinecobaltiimsulfato

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