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7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione

In the title mol­ecule, C(24)H(22)O(8), the mean planes of the two coumarin units are inclined to each other at a dihedral angle of 79.93 (3)°. The attached meth­oxy groups form torsion angles of 7.65 (19) and 78.36 (14)° with respect to one coumarin unit, and angles of 9.01 (16) and 99.08 (11)° wit...

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Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Parveen, Mehtab, Khanam, Zakia, Ghalib, Raza Murad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969715/
https://www.ncbi.nlm.nih.gov/pubmed/21583178
http://dx.doi.org/10.1107/S1600536809018029
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Parveen, Mehtab
Khanam, Zakia
Ghalib, Raza Murad
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Parveen, Mehtab
Khanam, Zakia
Ghalib, Raza Murad
author_sort Fun, Hoong-Kun
collection PubMed
description In the title mol­ecule, C(24)H(22)O(8), the mean planes of the two coumarin units are inclined to each other at a dihedral angle of 79.93 (3)°. The attached meth­oxy groups form torsion angles of 7.65 (19) and 78.36 (14)° with respect to one coumarin unit, and angles of 9.01 (16) and 99.08 (11)° with respect to the other coumarin unit. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect pairs of mol­ecules to form dimers, generating R (2) (2)(16) and R (2) (2)(18) rings; the dimers are linked by further weak inter­molecular C—H⋯O hydrogen bonds, forming extended chains. Additional stabil­ization is provided by weak C—H⋯π inter­actions.
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spelling pubmed-29697152010-12-30 7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione Fun, Hoong-Kun Jebas, Samuel Robinson Parveen, Mehtab Khanam, Zakia Ghalib, Raza Murad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(22)O(8), the mean planes of the two coumarin units are inclined to each other at a dihedral angle of 79.93 (3)°. The attached meth­oxy groups form torsion angles of 7.65 (19) and 78.36 (14)° with respect to one coumarin unit, and angles of 9.01 (16) and 99.08 (11)° with respect to the other coumarin unit. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect pairs of mol­ecules to form dimers, generating R (2) (2)(16) and R (2) (2)(18) rings; the dimers are linked by further weak inter­molecular C—H⋯O hydrogen bonds, forming extended chains. Additional stabil­ization is provided by weak C—H⋯π inter­actions. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969715/ /pubmed/21583178 http://dx.doi.org/10.1107/S1600536809018029 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Parveen, Mehtab
Khanam, Zakia
Ghalib, Raza Murad
7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
title 7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
title_full 7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
title_fullStr 7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
title_full_unstemmed 7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
title_short 7,7′,8,8′-Tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
title_sort 7,7′,8,8′-tetra­meth­oxy-4,4′-dimethyl-3,5′-bichromene-2,2′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969715/
https://www.ncbi.nlm.nih.gov/pubmed/21583178
http://dx.doi.org/10.1107/S1600536809018029
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