Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate

The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetra­fluoridoborate hexa­hydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously r...

Descripción completa

Detalles Bibliográficos
Autores principales: Brown, Krystal L., Crundwell, Guy, Westcott, Barry L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969716/
https://www.ncbi.nlm.nih.gov/pubmed/21583009
http://dx.doi.org/10.1107/S1600536809016973
Descripción
Sumario:The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetra­fluoridoborate hexa­hydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously reported salts and exhibits Cu—O bonds deviating by 25 degrees from an octa­hedral geometry by the so-called ‘off-axis angle’ distortion. The BF(4) (−) anion exhibits a two site disorder of the fluorine atoms [ratio 0.210 (8):0.790 (8)].

Ejemplares similares