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Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate

The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetra­fluoridoborate hexa­hydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously r...

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Detalles Bibliográficos
Autores principales: Brown, Krystal L., Crundwell, Guy, Westcott, Barry L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969716/
https://www.ncbi.nlm.nih.gov/pubmed/21583009
http://dx.doi.org/10.1107/S1600536809016973
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author Brown, Krystal L.
Crundwell, Guy
Westcott, Barry L.
author_facet Brown, Krystal L.
Crundwell, Guy
Westcott, Barry L.
author_sort Brown, Krystal L.
collection PubMed
description The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetra­fluoridoborate hexa­hydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously reported salts and exhibits Cu—O bonds deviating by 25 degrees from an octa­hedral geometry by the so-called ‘off-axis angle’ distortion. The BF(4) (−) anion exhibits a two site disorder of the fluorine atoms [ratio 0.210 (8):0.790 (8)].
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spelling pubmed-29697162010-12-30 Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate Brown, Krystal L. Crundwell, Guy Westcott, Barry L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetra­fluoridoborate hexa­hydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously reported salts and exhibits Cu—O bonds deviating by 25 degrees from an octa­hedral geometry by the so-called ‘off-axis angle’ distortion. The BF(4) (−) anion exhibits a two site disorder of the fluorine atoms [ratio 0.210 (8):0.790 (8)]. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969716/ /pubmed/21583009 http://dx.doi.org/10.1107/S1600536809016973 Text en © Brown et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brown, Krystal L.
Crundwell, Guy
Westcott, Barry L.
Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate
title Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate
title_full Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate
title_fullStr Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate
title_full_unstemmed Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate
title_short Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) bis­(tetra­fluorido­borate) dihydrate
title_sort bis(di-2-pyridylmethane­diol-κ(3) n,o,n′)copper(ii) bis­(tetra­fluorido­borate) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969716/
https://www.ncbi.nlm.nih.gov/pubmed/21583009
http://dx.doi.org/10.1107/S1600536809016973
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