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Bis(di-2-pyridylmethanediol-κ(3) N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate
The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetrafluoridoborate hexahydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously r...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969716/ https://www.ncbi.nlm.nih.gov/pubmed/21583009 http://dx.doi.org/10.1107/S1600536809016973 |
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author | Brown, Krystal L. Crundwell, Guy Westcott, Barry L. |
author_facet | Brown, Krystal L. Crundwell, Guy Westcott, Barry L. |
author_sort | Brown, Krystal L. |
collection | PubMed |
description | The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetrafluoridoborate hexahydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously reported salts and exhibits Cu—O bonds deviating by 25 degrees from an octahedral geometry by the so-called ‘off-axis angle’ distortion. The BF(4) (−) anion exhibits a two site disorder of the fluorine atoms [ratio 0.210 (8):0.790 (8)]. |
format | Text |
id | pubmed-2969716 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29697162010-12-30 Bis(di-2-pyridylmethanediol-κ(3) N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate Brown, Krystal L. Crundwell, Guy Westcott, Barry L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetrafluoridoborate hexahydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously reported salts and exhibits Cu—O bonds deviating by 25 degrees from an octahedral geometry by the so-called ‘off-axis angle’ distortion. The BF(4) (−) anion exhibits a two site disorder of the fluorine atoms [ratio 0.210 (8):0.790 (8)]. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969716/ /pubmed/21583009 http://dx.doi.org/10.1107/S1600536809016973 Text en © Brown et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Brown, Krystal L. Crundwell, Guy Westcott, Barry L. Bis(di-2-pyridylmethanediol-κ(3) N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate |
title | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate |
title_full | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate |
title_fullStr | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate |
title_full_unstemmed | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate |
title_short | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)copper(II) bis(tetrafluoridoborate) dihydrate |
title_sort | bis(di-2-pyridylmethanediol-κ(3)
n,o,n′)copper(ii) bis(tetrafluoridoborate) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969716/ https://www.ncbi.nlm.nih.gov/pubmed/21583009 http://dx.doi.org/10.1107/S1600536809016973 |
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