Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]

The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol­ecule and there is a crystallographic inversion centre in this mol­ecule. Each Al atom is penta­coordinated by one N atom and tw...

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Detalles Bibliográficos
Autores principales: Li, Chen-Yu, Lin, Chia-Her, Ko, Bao-Tsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969717/
https://www.ncbi.nlm.nih.gov/pubmed/21583031
http://dx.doi.org/10.1107/S1600536809018492
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author Li, Chen-Yu
Lin, Chia-Her
Ko, Bao-Tsan
author_facet Li, Chen-Yu
Lin, Chia-Her
Ko, Bao-Tsan
author_sort Li, Chen-Yu
collection PubMed
description The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol­ecule and there is a crystallographic inversion centre in this mol­ecule. Each Al atom is penta­coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal–bipyramidal environment.
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spelling pubmed-29697172010-12-30 Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)] Li, Chen-Yu Lin, Chia-Her Ko, Bao-Tsan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol­ecule and there is a crystallographic inversion centre in this mol­ecule. Each Al atom is penta­coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal–bipyramidal environment. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969717/ /pubmed/21583031 http://dx.doi.org/10.1107/S1600536809018492 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chen-Yu
Lin, Chia-Her
Ko, Bao-Tsan
Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]
title Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]
title_full Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]
title_fullStr Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]
title_full_unstemmed Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]
title_short Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(III)]
title_sort bis[μ-2-(2h-benzotriazol-2-yl)-4-methyl­phenolato]bis­[dimethyl­aluminium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969717/
https://www.ncbi.nlm.nih.gov/pubmed/21583031
http://dx.doi.org/10.1107/S1600536809018492
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