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(E)-1-Methyl-4-[2-(2-naphth­yl)vin­yl]pyridinium iodide

In the title compound, C(18)H(16)N(+)·I(−), the cation is disordered over two orientations related by a 180° rotation about its long axis with occupancies of 0.554 (7) and 0.446 (7). Both disorder components exist in an E configuration. The dihedral angle between the pyridinium ring and the naphthal...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chanawanno, Kullapa, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969718/
https://www.ncbi.nlm.nih.gov/pubmed/21583250
http://dx.doi.org/10.1107/S1600536809019114
Descripción
Sumario:In the title compound, C(18)H(16)N(+)·I(−), the cation is disordered over two orientations related by a 180° rotation about its long axis with occupancies of 0.554 (7) and 0.446 (7). Both disorder components exist in an E configuration. The dihedral angle between the pyridinium ring and the naphthalene ring system is 4.7 (6)° in the major disorder component and 1.6 (8)° in the minor component. In the crystal structure, centrosymmetrically related cations are stacked along the a axis, with significant π–π inter­actions between the pyridinium ring and the naphthalene ring system [centroid-centroid distance = 3.442 (9) Å]. The iodide ions are located between adjacent columns of cations. The cations are linked to the iodide ions by C—H⋯I inter­actions. Weak C—H⋯π inter­actions involving the methyl group are also observed.