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(E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide
In the title compound, C(18)H(16)N(+)·I(−), the cation is disordered over two orientations related by a 180° rotation about its long axis with occupancies of 0.554 (7) and 0.446 (7). Both disorder components exist in an E configuration. The dihedral angle between the pyridinium ring and the naphthal...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969718/ https://www.ncbi.nlm.nih.gov/pubmed/21583250 http://dx.doi.org/10.1107/S1600536809019114 |
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author | Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada |
author_facet | Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, C(18)H(16)N(+)·I(−), the cation is disordered over two orientations related by a 180° rotation about its long axis with occupancies of 0.554 (7) and 0.446 (7). Both disorder components exist in an E configuration. The dihedral angle between the pyridinium ring and the naphthalene ring system is 4.7 (6)° in the major disorder component and 1.6 (8)° in the minor component. In the crystal structure, centrosymmetrically related cations are stacked along the a axis, with significant π–π interactions between the pyridinium ring and the naphthalene ring system [centroid-centroid distance = 3.442 (9) Å]. The iodide ions are located between adjacent columns of cations. The cations are linked to the iodide ions by C—H⋯I interactions. Weak C—H⋯π interactions involving the methyl group are also observed. |
format | Text |
id | pubmed-2969718 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29697182010-12-30 (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)N(+)·I(−), the cation is disordered over two orientations related by a 180° rotation about its long axis with occupancies of 0.554 (7) and 0.446 (7). Both disorder components exist in an E configuration. The dihedral angle between the pyridinium ring and the naphthalene ring system is 4.7 (6)° in the major disorder component and 1.6 (8)° in the minor component. In the crystal structure, centrosymmetrically related cations are stacked along the a axis, with significant π–π interactions between the pyridinium ring and the naphthalene ring system [centroid-centroid distance = 3.442 (9) Å]. The iodide ions are located between adjacent columns of cations. The cations are linked to the iodide ions by C—H⋯I interactions. Weak C—H⋯π interactions involving the methyl group are also observed. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969718/ /pubmed/21583250 http://dx.doi.org/10.1107/S1600536809019114 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide |
title | (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide
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title_full | (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide
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title_fullStr | (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide
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title_full_unstemmed | (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide
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title_short | (E)-1-Methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide
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title_sort | (e)-1-methyl-4-[2-(2-naphthyl)vinyl]pyridinium iodide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969718/ https://www.ncbi.nlm.nih.gov/pubmed/21583250 http://dx.doi.org/10.1107/S1600536809019114 |
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