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Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate
The title compound, [Eu(C(12)H(9.33)N(2)O)(3)]NO(3), was obtained by the reaction of Eu(NO(3))·3H(2)O and the Schiff base ligand 2-(2-pyridyliminomethyl)phenol. The Eu atom is located on a threefold rotation axis and is nine-coordinated by three tridentate Schiff base ligands in a distorted tricap...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969734/ https://www.ncbi.nlm.nih.gov/pubmed/21583052 http://dx.doi.org/10.1107/S1600536809017206 |
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author | Zhao, Qi-Hua Chen, Hong-Yan Li, Li-Nan Xie, Ming-Jin |
author_facet | Zhao, Qi-Hua Chen, Hong-Yan Li, Li-Nan Xie, Ming-Jin |
author_sort | Zhao, Qi-Hua |
collection | PubMed |
description | The title compound, [Eu(C(12)H(9.33)N(2)O)(3)]NO(3), was obtained by the reaction of Eu(NO(3))·3H(2)O and the Schiff base ligand 2-(2-pyridyliminomethyl)phenol. The Eu atom is located on a threefold rotation axis and is nine-coordinated by three tridentate Schiff base ligands in a distorted tricapped trigonal-prismatic geometry. The O atom at the phenol hydroxy group is partially deprotonated and the H atoms are modelled with one-third occupancy according to the space group R [Image: see text]. Offset face-to-face π–π [centroid–centroid distance = 3.886 (3) Å] and edge-to-face C—H⋯π interactions are found between adjacent molecules. An intramolecular O—H⋯N hydrogen bond is also present. |
format | Text |
id | pubmed-2969734 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29697342010-12-30 Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate Zhao, Qi-Hua Chen, Hong-Yan Li, Li-Nan Xie, Ming-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Eu(C(12)H(9.33)N(2)O)(3)]NO(3), was obtained by the reaction of Eu(NO(3))·3H(2)O and the Schiff base ligand 2-(2-pyridyliminomethyl)phenol. The Eu atom is located on a threefold rotation axis and is nine-coordinated by three tridentate Schiff base ligands in a distorted tricapped trigonal-prismatic geometry. The O atom at the phenol hydroxy group is partially deprotonated and the H atoms are modelled with one-third occupancy according to the space group R [Image: see text]. Offset face-to-face π–π [centroid–centroid distance = 3.886 (3) Å] and edge-to-face C—H⋯π interactions are found between adjacent molecules. An intramolecular O—H⋯N hydrogen bond is also present. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969734/ /pubmed/21583052 http://dx.doi.org/10.1107/S1600536809017206 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Qi-Hua Chen, Hong-Yan Li, Li-Nan Xie, Ming-Jin Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate |
title | Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate |
title_full | Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate |
title_fullStr | Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate |
title_full_unstemmed | Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate |
title_short | Tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(III) nitrate |
title_sort | tris[2-(2-pyridyliminomethyl)phenolato(0.67−)]europium(iii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969734/ https://www.ncbi.nlm.nih.gov/pubmed/21583052 http://dx.doi.org/10.1107/S1600536809017206 |
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