Cargando…

Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate

The title compound, [Eu(C(12)H(9.33)N(2)O)(3)]NO(3), was obtained by the reaction of Eu(NO(3))·3H(2)O and the Schiff base ligand 2-(2-pyridylimino­meth­yl)phenol. The Eu atom is located on a threefold rotation axis and is nine-coordinated by three tridentate Schiff base ligands in a distorted tricap...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Qi-Hua, Chen, Hong-Yan, Li, Li-Nan, Xie, Ming-Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969734/
https://www.ncbi.nlm.nih.gov/pubmed/21583052
http://dx.doi.org/10.1107/S1600536809017206
_version_ 1782190242974924800
author Zhao, Qi-Hua
Chen, Hong-Yan
Li, Li-Nan
Xie, Ming-Jin
author_facet Zhao, Qi-Hua
Chen, Hong-Yan
Li, Li-Nan
Xie, Ming-Jin
author_sort Zhao, Qi-Hua
collection PubMed
description The title compound, [Eu(C(12)H(9.33)N(2)O)(3)]NO(3), was obtained by the reaction of Eu(NO(3))·3H(2)O and the Schiff base ligand 2-(2-pyridylimino­meth­yl)phenol. The Eu atom is located on a threefold rotation axis and is nine-coordinated by three tridentate Schiff base ligands in a distorted tricapped trigonal-prismatic geometry. The O atom at the phenol hydr­oxy group is partially deprotonated and the H atoms are modelled with one-third occupancy according to the space group R [Image: see text]. Offset face-to-face π–π [centroid–centroid distance = 3.886 (3) Å] and edge-to-face C—H⋯π inter­actions are found between adjacent mol­ecules. An intra­molecular O—H⋯N hydrogen bond is also present.
format Text
id pubmed-2969734
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29697342010-12-30 Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate Zhao, Qi-Hua Chen, Hong-Yan Li, Li-Nan Xie, Ming-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Eu(C(12)H(9.33)N(2)O)(3)]NO(3), was obtained by the reaction of Eu(NO(3))·3H(2)O and the Schiff base ligand 2-(2-pyridylimino­meth­yl)phenol. The Eu atom is located on a threefold rotation axis and is nine-coordinated by three tridentate Schiff base ligands in a distorted tricapped trigonal-prismatic geometry. The O atom at the phenol hydr­oxy group is partially deprotonated and the H atoms are modelled with one-third occupancy according to the space group R [Image: see text]. Offset face-to-face π–π [centroid–centroid distance = 3.886 (3) Å] and edge-to-face C—H⋯π inter­actions are found between adjacent mol­ecules. An intra­molecular O—H⋯N hydrogen bond is also present. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969734/ /pubmed/21583052 http://dx.doi.org/10.1107/S1600536809017206 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Qi-Hua
Chen, Hong-Yan
Li, Li-Nan
Xie, Ming-Jin
Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate
title Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate
title_full Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate
title_fullStr Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate
title_full_unstemmed Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate
title_short Tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(III) nitrate
title_sort tris[2-(2-pyridylimino­meth­yl)phenol­ato(0.67−)]europium(iii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969734/
https://www.ncbi.nlm.nih.gov/pubmed/21583052
http://dx.doi.org/10.1107/S1600536809017206
work_keys_str_mv AT zhaoqihua tris22pyridyliminomethylphenolato067europiumiiinitrate
AT chenhongyan tris22pyridyliminomethylphenolato067europiumiiinitrate
AT lilinan tris22pyridyliminomethylphenolato067europiumiiinitrate
AT xiemingjin tris22pyridyliminomethylphenolato067europiumiiinitrate