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1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate
The title Schiff base compound, C(19)H(18)N(2)O, was prepared by the reaction of equimolar quantities of 2-hydroxy-1-naphthaldehyde with N-phenylethane-1,2-diamine in a methanol solution. The molecule adopts a zwitterionic conformation with the naphthyl OH group deprotonated and the imine N atom...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969739/ https://www.ncbi.nlm.nih.gov/pubmed/21583245 http://dx.doi.org/10.1107/S1600536809019096 |
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author | Hao, Yu-Mei |
author_facet | Hao, Yu-Mei |
author_sort | Hao, Yu-Mei |
collection | PubMed |
description | The title Schiff base compound, C(19)H(18)N(2)O, was prepared by the reaction of equimolar quantities of 2-hydroxy-1-naphthaldehyde with N-phenylethane-1,2-diamine in a methanol solution. The molecule adopts a zwitterionic conformation with the naphthyl OH group deprotonated and the imine N atom protonated. An intramolecular N—H⋯O hydrogen bond forms between them. The dihedral angle between the benzene ring and the naphthyl system is 86.9 (2)°. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis. |
format | Text |
id | pubmed-2969739 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29697392010-12-30 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate Hao, Yu-Mei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(19)H(18)N(2)O, was prepared by the reaction of equimolar quantities of 2-hydroxy-1-naphthaldehyde with N-phenylethane-1,2-diamine in a methanol solution. The molecule adopts a zwitterionic conformation with the naphthyl OH group deprotonated and the imine N atom protonated. An intramolecular N—H⋯O hydrogen bond forms between them. The dihedral angle between the benzene ring and the naphthyl system is 86.9 (2)°. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969739/ /pubmed/21583245 http://dx.doi.org/10.1107/S1600536809019096 Text en © Yu-Mei Hao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hao, Yu-Mei 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate |
title | 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate |
title_full | 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate |
title_fullStr | 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate |
title_full_unstemmed | 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate |
title_short | 1-[(2-Anilinoethyl)iminiomethyl]-2-naphtholate |
title_sort | 1-[(2-anilinoethyl)iminiomethyl]-2-naphtholate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969739/ https://www.ncbi.nlm.nih.gov/pubmed/21583245 http://dx.doi.org/10.1107/S1600536809019096 |
work_keys_str_mv | AT haoyumei 12anilinoethyliminiomethyl2naphtholate |