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Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1)
The Sn atom in the title substituted pyridinium stannate bromo-3,4-dichlorobenzene solvate, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(3)Cl(2))(2)]·C(6)H(3)BrCl(2), lies on a twofold axis within an octahedral C(2)Br(4) donor set. Each cation forms an N—H⋯Br hydrogen bond to one of the Br atoms of the anion....
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969743/ https://www.ncbi.nlm.nih.gov/pubmed/21583025 http://dx.doi.org/10.1107/S1600536809017590 |
| _version_ | 1782190245840683008 |
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| author | Koon, Yau Chin Lo, Kong Mun Ng, Seik Weng |
| author_facet | Koon, Yau Chin Lo, Kong Mun Ng, Seik Weng |
| author_sort | Koon, Yau Chin |
| collection | PubMed |
| description | The Sn atom in the title substituted pyridinium stannate bromo-3,4-dichlorobenzene solvate, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(3)Cl(2))(2)]·C(6)H(3)BrCl(2), lies on a twofold axis within an octahedral C(2)Br(4) donor set. Each cation forms an N—H⋯Br hydrogen bond to one of the Br atoms of the anion. The solvent molecule is disordered about the twofold rotation axis with equal occupancy. The crystal under investigation was non-merohedrally twinned, with a twin component ratio of 0.76:0.24. |
| format | Text |
| id | pubmed-2969743 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29697432010-12-30 Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) Koon, Yau Chin Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title substituted pyridinium stannate bromo-3,4-dichlorobenzene solvate, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(3)Cl(2))(2)]·C(6)H(3)BrCl(2), lies on a twofold axis within an octahedral C(2)Br(4) donor set. Each cation forms an N—H⋯Br hydrogen bond to one of the Br atoms of the anion. The solvent molecule is disordered about the twofold rotation axis with equal occupancy. The crystal under investigation was non-merohedrally twinned, with a twin component ratio of 0.76:0.24. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969743/ /pubmed/21583025 http://dx.doi.org/10.1107/S1600536809017590 Text en © Koon et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Koon, Yau Chin Lo, Kong Mun Ng, Seik Weng Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) |
| title | Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) |
| title_full | Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) |
| title_fullStr | Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) |
| title_full_unstemmed | Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) |
| title_short | Bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(IV)–1-bromo-3,4-dichlorobenzene (1/1) |
| title_sort | bis[4-(dimethylamino)pyridinium] tetrabromidobis(3,4-dichlorophenyl)stannate(iv)–1-bromo-3,4-dichlorobenzene (1/1) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969743/ https://www.ncbi.nlm.nih.gov/pubmed/21583025 http://dx.doi.org/10.1107/S1600536809017590 |
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