trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)

In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa­hedral environment. The main geometric parameters are Pt—N = 1.960 (5) Å, and Pt—Cl = 2.3177 (12) and 2.3196 (12) Å. The N C bond is a typical triple bond [1.137 (7) Å]. The Pt—N C—C un...

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Detalles Bibliográficos
Autores principales: Bokach, Nadezhda A., Kukushkin, Vadim Yu., Haukka, Matti
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969749/
https://www.ncbi.nlm.nih.gov/pubmed/21583004
http://dx.doi.org/10.1107/S1600536809016535
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author Bokach, Nadezhda A.
Kukushkin, Vadim Yu.
Haukka, Matti
author_facet Bokach, Nadezhda A.
Kukushkin, Vadim Yu.
Haukka, Matti
author_sort Bokach, Nadezhda A.
collection PubMed
description In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa­hedral environment. The main geometric parameters are Pt—N = 1.960 (5) Å, and Pt—Cl = 2.3177 (12) and 2.3196 (12) Å. The N C bond is a typical triple bond [1.137 (7) Å]. The Pt—N C—C unit is almost linear, with Pt—N—C and N—C—C angles of 174.6 (4) and 177.1 (6)°, respectively.
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spelling pubmed-29697492010-12-30 trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV) Bokach, Nadezhda A. Kukushkin, Vadim Yu. Haukka, Matti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa­hedral environment. The main geometric parameters are Pt—N = 1.960 (5) Å, and Pt—Cl = 2.3177 (12) and 2.3196 (12) Å. The N C bond is a typical triple bond [1.137 (7) Å]. The Pt—N C—C unit is almost linear, with Pt—N—C and N—C—C angles of 174.6 (4) and 177.1 (6)°, respectively. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969749/ /pubmed/21583004 http://dx.doi.org/10.1107/S1600536809016535 Text en © Bokach et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bokach, Nadezhda A.
Kukushkin, Vadim Yu.
Haukka, Matti
trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)
title trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)
title_full trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)
title_fullStr trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)
title_full_unstemmed trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)
title_short trans-Tetra­chloridobis(diphenyl­aceto­nitrile)platinum(IV)
title_sort trans-tetra­chloridobis(diphenyl­aceto­nitrile)platinum(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969749/
https://www.ncbi.nlm.nih.gov/pubmed/21583004
http://dx.doi.org/10.1107/S1600536809016535
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AT haukkamatti transtetrachloridobisdiphenylacetonitrileplatinumiv

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