Aqua­(propane­dioato-κ(2) O (1),O (3))[2-(1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]nickel(II) trihydrate

In the title mononuclear complex, [Ni(C(3)H(2)O(4))(C(15)H(10)N(4))(H(2)O)]·3H(2)O, the metal center is coordinated in a distorted NiN(3)O(3) geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the components into a two-dimensional network. In addition, there are weak π–π s...

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Detalles Bibliográficos
Autores principales: Yan, Huai Yi, Hu, Tai Qiu, Shi, Jing Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969757/
https://www.ncbi.nlm.nih.gov/pubmed/21583013
http://dx.doi.org/10.1107/S1600536809017188
Descripción
Sumario:In the title mononuclear complex, [Ni(C(3)H(2)O(4))(C(15)H(10)N(4))(H(2)O)]·3H(2)O, the metal center is coordinated in a distorted NiN(3)O(3) geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the components into a two-dimensional network. In addition, there are weak π–π stacking inter­actions between symmetry-related phenanthroline rings, with a centroid–centroid distance of 3.6253 (17) Å.

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