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Aqua(propanedioato-κ(2) O (1),O (3))[2-(1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]nickel(II) trihydrate
In the title mononuclear complex, [Ni(C(3)H(2)O(4))(C(15)H(10)N(4))(H(2)O)]·3H(2)O, the metal center is coordinated in a distorted NiN(3)O(3) geometry. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the components into a two-dimensional network. In addition, there are weak π–π s...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969757/ https://www.ncbi.nlm.nih.gov/pubmed/21583013 http://dx.doi.org/10.1107/S1600536809017188 |
| _version_ | 1782190250634772480 |
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| author | Yan, Huai Yi Hu, Tai Qiu Shi, Jing Min |
| author_facet | Yan, Huai Yi Hu, Tai Qiu Shi, Jing Min |
| author_sort | Yan, Huai Yi |
| collection | PubMed |
| description | In the title mononuclear complex, [Ni(C(3)H(2)O(4))(C(15)H(10)N(4))(H(2)O)]·3H(2)O, the metal center is coordinated in a distorted NiN(3)O(3) geometry. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the components into a two-dimensional network. In addition, there are weak π–π stacking interactions between symmetry-related phenanthroline rings, with a centroid–centroid distance of 3.6253 (17) Å. |
| format | Text |
| id | pubmed-2969757 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29697572010-12-30 Aqua(propanedioato-κ(2) O (1),O (3))[2-(1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]nickel(II) trihydrate Yan, Huai Yi Hu, Tai Qiu Shi, Jing Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ni(C(3)H(2)O(4))(C(15)H(10)N(4))(H(2)O)]·3H(2)O, the metal center is coordinated in a distorted NiN(3)O(3) geometry. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the components into a two-dimensional network. In addition, there are weak π–π stacking interactions between symmetry-related phenanthroline rings, with a centroid–centroid distance of 3.6253 (17) Å. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969757/ /pubmed/21583013 http://dx.doi.org/10.1107/S1600536809017188 Text en © Yan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yan, Huai Yi Hu, Tai Qiu Shi, Jing Min Aqua(propanedioato-κ(2) O (1),O (3))[2-(1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]nickel(II) trihydrate |
| title | Aqua(propanedioato-κ(2)
O
(1),O
(3))[2-(1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]nickel(II) trihydrate |
| title_full | Aqua(propanedioato-κ(2)
O
(1),O
(3))[2-(1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]nickel(II) trihydrate |
| title_fullStr | Aqua(propanedioato-κ(2)
O
(1),O
(3))[2-(1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]nickel(II) trihydrate |
| title_full_unstemmed | Aqua(propanedioato-κ(2)
O
(1),O
(3))[2-(1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]nickel(II) trihydrate |
| title_short | Aqua(propanedioato-κ(2)
O
(1),O
(3))[2-(1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]nickel(II) trihydrate |
| title_sort | aqua(propanedioato-κ(2)
o
(1),o
(3))[2-(1h-pyrazol-1-yl-κn
(2))-1,10-phenanthroline-κ(2)
n,n′]nickel(ii) trihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969757/ https://www.ncbi.nlm.nih.gov/pubmed/21583013 http://dx.doi.org/10.1107/S1600536809017188 |
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