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4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside

The title compound, C(21)H(24)O(11), crystallizes exclusively as the β-anomer. The substituent of the protected sugar at position C-3 is in the axial position, while all other groups are in equatorial positions. The pyran­oside ring adopts a stable chair conformation.

Detalles Bibliográficos
Autores principales: Ye, Ding, Zhang, Kuan, Chen, Hua-feng, Yin, Shu-fan, Li, Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969774/
https://www.ncbi.nlm.nih.gov/pubmed/21583191
http://dx.doi.org/10.1107/S1600536809018248
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author Ye, Ding
Zhang, Kuan
Chen, Hua-feng
Yin, Shu-fan
Li, Ying
author_facet Ye, Ding
Zhang, Kuan
Chen, Hua-feng
Yin, Shu-fan
Li, Ying
author_sort Ye, Ding
collection PubMed
description The title compound, C(21)H(24)O(11), crystallizes exclusively as the β-anomer. The substituent of the protected sugar at position C-3 is in the axial position, while all other groups are in equatorial positions. The pyran­oside ring adopts a stable chair conformation.
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spelling pubmed-29697742010-12-30 4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside Ye, Ding Zhang, Kuan Chen, Hua-feng Yin, Shu-fan Li, Ying Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(24)O(11), crystallizes exclusively as the β-anomer. The substituent of the protected sugar at position C-3 is in the axial position, while all other groups are in equatorial positions. The pyran­oside ring adopts a stable chair conformation. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969774/ /pubmed/21583191 http://dx.doi.org/10.1107/S1600536809018248 Text en © Ye et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ye, Ding
Zhang, Kuan
Chen, Hua-feng
Yin, Shu-fan
Li, Ying
4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside
title 4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside
title_full 4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside
title_fullStr 4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside
title_full_unstemmed 4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside
title_short 4-Formyl­phenyl 2,3,4,6-tetra-O-acetyl-β-d-allopyran­oside
title_sort 4-formyl­phenyl 2,3,4,6-tetra-o-acetyl-β-d-allopyran­oside
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969774/
https://www.ncbi.nlm.nih.gov/pubmed/21583191
http://dx.doi.org/10.1107/S1600536809018248
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