trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate

In the title compound, [Co(C(10)H(12)N(2)O)(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, the Co(II) ion, located on an inversion center, is trans-coordinated by two N,O-bidentate chelating (E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one ligands and by two water mol­ecules in a slightly distorted octa­hedral...

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Detalles Bibliográficos
Autor principal: Bi, Jian-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969776/
https://www.ncbi.nlm.nih.gov/pubmed/21583001
http://dx.doi.org/10.1107/S1600536809016845
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author Bi, Jian-Hong
author_facet Bi, Jian-Hong
author_sort Bi, Jian-Hong
collection PubMed
description In the title compound, [Co(C(10)H(12)N(2)O)(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, the Co(II) ion, located on an inversion center, is trans-coordinated by two N,O-bidentate chelating (E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one ligands and by two water mol­ecules in a slightly distorted octa­hedral geometry. Inter­molecular O—H⋯O hydrogen bonds link the cations, anions and water mol­ecules into layers parallel to the ac plane. The crystal packing also exhibits weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-29697762010-12-30 trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate Bi, Jian-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(12)N(2)O)(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, the Co(II) ion, located on an inversion center, is trans-coordinated by two N,O-bidentate chelating (E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one ligands and by two water mol­ecules in a slightly distorted octa­hedral geometry. Inter­molecular O—H⋯O hydrogen bonds link the cations, anions and water mol­ecules into layers parallel to the ac plane. The crystal packing also exhibits weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969776/ /pubmed/21583001 http://dx.doi.org/10.1107/S1600536809016845 Text en © Jian-Hong Bi 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bi, Jian-Hong
trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate
title trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate
title_full trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate
title_fullStr trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate
title_full_unstemmed trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate
title_short trans-Diaqua­bis[(E)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) N (1),O]cobalt(II) dinitrate dihydrate
title_sort trans-diaqua­bis[(e)-3-(dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ(2) n (1),o]cobalt(ii) dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969776/
https://www.ncbi.nlm.nih.gov/pubmed/21583001
http://dx.doi.org/10.1107/S1600536809016845
work_keys_str_mv AT bijianhong transdiaquabise3dimethylamino12pyridylprop2en1onek2n1ocobaltiidinitratedihydrate

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