Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate

In the title salt, Na(+)·C(7)H(7)ClNO(2)S(−)·1.5H(2)O, one of the water mol­ecules lies on a twofold axis. The sodium ion shows an O(6) octa­hedral coordination defined by three water O atoms and three sulfonyl O atoms derived from three different anions. The S—N distance of 1.5898 (19) Å is consist...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969781/
https://www.ncbi.nlm.nih.gov/pubmed/21583054
http://dx.doi.org/10.1107/S1600536809019989
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author Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title salt, Na(+)·C(7)H(7)ClNO(2)S(−)·1.5H(2)O, one of the water mol­ecules lies on a twofold axis. The sodium ion shows an O(6) octa­hedral coordination defined by three water O atoms and three sulfonyl O atoms derived from three different anions. The S—N distance of 1.5898 (19) Å is consistent with an S=N double bond. The crystal structure is stabilized by N—H⋯O and O—H⋯Cl hydrogen bonds.
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spelling pubmed-29697812010-12-30 Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, Na(+)·C(7)H(7)ClNO(2)S(−)·1.5H(2)O, one of the water mol­ecules lies on a twofold axis. The sodium ion shows an O(6) octa­hedral coordination defined by three water O atoms and three sulfonyl O atoms derived from three different anions. The S—N distance of 1.5898 (19) Å is consistent with an S=N double bond. The crystal structure is stabilized by N—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969781/ /pubmed/21583054 http://dx.doi.org/10.1107/S1600536809019989 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
title Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
title_full Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
title_fullStr Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
title_full_unstemmed Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
title_short Sodium N-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
title_sort sodium n-chloro-2-methyl­benzene­sulfonamidate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969781/
https://www.ncbi.nlm.nih.gov/pubmed/21583054
http://dx.doi.org/10.1107/S1600536809019989
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