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Bis(acetato-κ(2) O,O′)bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
In the title compound, [Cu(C(2)H(3)O(2))(2)(C(5)H(8)N(2))(2)], the Cu(II) atom has a distorted tetragonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetat...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969789/ https://www.ncbi.nlm.nih.gov/pubmed/21583048 http://dx.doi.org/10.1107/S1600536809019400 |
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author | Davydenko, Yuliya M. Fritsky, Igor O. Pavlenko, Vadim O. Meyer, Franc Dechert, Sebastian |
author_facet | Davydenko, Yuliya M. Fritsky, Igor O. Pavlenko, Vadim O. Meyer, Franc Dechert, Sebastian |
author_sort | Davydenko, Yuliya M. |
collection | PubMed |
description | In the title compound, [Cu(C(2)H(3)O(2))(2)(C(5)H(8)N(2))(2)], the Cu(II) atom has a distorted tetragonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetate groups provide elongated Cu—O axial contacts, so that the acetates appear to be coordinated in a pseudo-chelate fashion. The pyrazole ligands are situated in cis positions with respect to each other. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming a one-dimensional chain. |
format | Text |
id | pubmed-2969789 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29697892010-12-30 Bis(acetato-κ(2) O,O′)bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) Davydenko, Yuliya M. Fritsky, Igor O. Pavlenko, Vadim O. Meyer, Franc Dechert, Sebastian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(3)O(2))(2)(C(5)H(8)N(2))(2)], the Cu(II) atom has a distorted tetragonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetate groups provide elongated Cu—O axial contacts, so that the acetates appear to be coordinated in a pseudo-chelate fashion. The pyrazole ligands are situated in cis positions with respect to each other. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming a one-dimensional chain. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969789/ /pubmed/21583048 http://dx.doi.org/10.1107/S1600536809019400 Text en © Davydenko et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Davydenko, Yuliya M. Fritsky, Igor O. Pavlenko, Vadim O. Meyer, Franc Dechert, Sebastian Bis(acetato-κ(2) O,O′)bis(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) |
title | Bis(acetato-κ(2)
O,O′)bis(3,5-dimethyl-1H-pyrazole-κN
(2))copper(II) |
title_full | Bis(acetato-κ(2)
O,O′)bis(3,5-dimethyl-1H-pyrazole-κN
(2))copper(II) |
title_fullStr | Bis(acetato-κ(2)
O,O′)bis(3,5-dimethyl-1H-pyrazole-κN
(2))copper(II) |
title_full_unstemmed | Bis(acetato-κ(2)
O,O′)bis(3,5-dimethyl-1H-pyrazole-κN
(2))copper(II) |
title_short | Bis(acetato-κ(2)
O,O′)bis(3,5-dimethyl-1H-pyrazole-κN
(2))copper(II) |
title_sort | bis(acetato-κ(2)
o,o′)bis(3,5-dimethyl-1h-pyrazole-κn
(2))copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969789/ https://www.ncbi.nlm.nih.gov/pubmed/21583048 http://dx.doi.org/10.1107/S1600536809019400 |
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