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Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)

In the title compound, [Cu(C(2)H(3)O(2))(2)(C(5)H(8)N(2))(2)], the Cu(II) atom has a distorted tetra­gonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetat...

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Autores principales: Davydenko, Yuliya M., Fritsky, Igor O., Pavlenko, Vadim O., Meyer, Franc, Dechert, Sebastian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969789/
https://www.ncbi.nlm.nih.gov/pubmed/21583048
http://dx.doi.org/10.1107/S1600536809019400
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author Davydenko, Yuliya M.
Fritsky, Igor O.
Pavlenko, Vadim O.
Meyer, Franc
Dechert, Sebastian
author_facet Davydenko, Yuliya M.
Fritsky, Igor O.
Pavlenko, Vadim O.
Meyer, Franc
Dechert, Sebastian
author_sort Davydenko, Yuliya M.
collection PubMed
description In the title compound, [Cu(C(2)H(3)O(2))(2)(C(5)H(8)N(2))(2)], the Cu(II) atom has a distorted tetra­gonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetate groups provide elongated Cu—O axial contacts, so that the acetates appear to be coordinated in a pseudo-chelate fashion. The pyrazole ligands are situated in cis positions with respect to each other. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming a one-dimensional chain.
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spelling pubmed-29697892010-12-30 Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II) Davydenko, Yuliya M. Fritsky, Igor O. Pavlenko, Vadim O. Meyer, Franc Dechert, Sebastian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(3)O(2))(2)(C(5)H(8)N(2))(2)], the Cu(II) atom has a distorted tetra­gonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetate groups provide elongated Cu—O axial contacts, so that the acetates appear to be coordinated in a pseudo-chelate fashion. The pyrazole ligands are situated in cis positions with respect to each other. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming a one-dimensional chain. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969789/ /pubmed/21583048 http://dx.doi.org/10.1107/S1600536809019400 Text en © Davydenko et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davydenko, Yuliya M.
Fritsky, Igor O.
Pavlenko, Vadim O.
Meyer, Franc
Dechert, Sebastian
Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
title Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
title_full Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
title_fullStr Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
title_full_unstemmed Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
title_short Bis(acetato-κ(2) O,O′)bis­(3,5-dimethyl-1H-pyrazole-κN (2))copper(II)
title_sort bis(acetato-κ(2) o,o′)bis­(3,5-dimethyl-1h-pyrazole-κn (2))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969789/
https://www.ncbi.nlm.nih.gov/pubmed/21583048
http://dx.doi.org/10.1107/S1600536809019400
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