Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate

The asymmetric unit of the title compound, [PtCl(2)(C(6)H(4)NO(2))(2)]·CH(3)CN, contains a neutral Pt(IV) complex and an acetonitrile solvent mol­ecule. In the complex, the Pt(4+) atom is six-coordinated in a distorted octa­hedral environment by two N atoms and two O atoms from two pyridine­carboxyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Kim, Nam-Ho, Hwang, In-Chul, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969797/
https://www.ncbi.nlm.nih.gov/pubmed/21583028
http://dx.doi.org/10.1107/S1600536809017966
_version_ 1782190262980706304
author Kim, Nam-Ho
Hwang, In-Chul
Ha, Kwang
author_facet Kim, Nam-Ho
Hwang, In-Chul
Ha, Kwang
author_sort Kim, Nam-Ho
collection PubMed
description The asymmetric unit of the title compound, [PtCl(2)(C(6)H(4)NO(2))(2)]·CH(3)CN, contains a neutral Pt(IV) complex and an acetonitrile solvent mol­ecule. In the complex, the Pt(4+) atom is six-coordinated in a distorted octa­hedral environment by two N atoms and two O atoms from two pyridine­carboxyl­ate (pic) ligands and two Cl atoms. The Cl atoms are cis with respect to each other. The compound displays inter- and intra­molecular C—H⋯O and C—H⋯Cl hydrogen bonding.
format Text
id pubmed-2969797
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29697972010-12-30 Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate Kim, Nam-Ho Hwang, In-Chul Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [PtCl(2)(C(6)H(4)NO(2))(2)]·CH(3)CN, contains a neutral Pt(IV) complex and an acetonitrile solvent mol­ecule. In the complex, the Pt(4+) atom is six-coordinated in a distorted octa­hedral environment by two N atoms and two O atoms from two pyridine­carboxyl­ate (pic) ligands and two Cl atoms. The Cl atoms are cis with respect to each other. The compound displays inter- and intra­molecular C—H⋯O and C—H⋯Cl hydrogen bonding. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969797/ /pubmed/21583028 http://dx.doi.org/10.1107/S1600536809017966 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Nam-Ho
Hwang, In-Chul
Ha, Kwang
Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate
title Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate
title_full Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate
title_fullStr Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate
title_full_unstemmed Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate
title_short Dichloridobis(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(IV) acetonitrile solvate
title_sort dichloridobis(pyridine-2-carboxyl­ato-κ(2) n,o)platinum(iv) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969797/
https://www.ncbi.nlm.nih.gov/pubmed/21583028
http://dx.doi.org/10.1107/S1600536809017966
work_keys_str_mv AT kimnamho dichloridobispyridine2carboxylatok2noplatinumivacetonitrilesolvate
AT hwanginchul dichloridobispyridine2carboxylatok2noplatinumivacetonitrilesolvate
AT hakwang dichloridobispyridine2carboxylatok2noplatinumivacetonitrilesolvate

Ejemplares similares