4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate

In the cation of the title compound, C(22)H(19)N(2) (+)·NO(3) (−), the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N—H⋯O...

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Detalles Bibliográficos
Autor principal: Cui, Li-Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969798/
https://www.ncbi.nlm.nih.gov/pubmed/21583212
http://dx.doi.org/10.1107/S1600536809018789
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author Cui, Li-Jing
author_facet Cui, Li-Jing
author_sort Cui, Li-Jing
collection PubMed
description In the cation of the title compound, C(22)H(19)N(2) (+)·NO(3) (−), the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N—H⋯O and N—H⋯(O,O) hydrogen bonds link the mol­ecules to form an infinite one-dimensional chain parallel to the c axis.
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spelling pubmed-29697982010-12-30 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate Cui, Li-Jing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound, C(22)H(19)N(2) (+)·NO(3) (−), the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N—H⋯O and N—H⋯(O,O) hydrogen bonds link the mol­ecules to form an infinite one-dimensional chain parallel to the c axis. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969798/ /pubmed/21583212 http://dx.doi.org/10.1107/S1600536809018789 Text en © Li-Jing Cui 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cui, Li-Jing
4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_full 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_fullStr 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_full_unstemmed 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_short 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_sort 4,5-diphenyl-2-p-tolyl-1h-imidazol-3-ium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969798/
https://www.ncbi.nlm.nih.gov/pubmed/21583212
http://dx.doi.org/10.1107/S1600536809018789
work_keys_str_mv AT cuilijing 45diphenyl2ptolyl1himidazol3iumnitrate

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