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1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate

In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral gr...

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Autores principales: Espinosa Leija, Armando, Hernández, Guadalupe, Cruz, Sandra, Bernès, Sylvain, Gutiérrez, René
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969804/
https://www.ncbi.nlm.nih.gov/pubmed/21583173
http://dx.doi.org/10.1107/S1600536809017528
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author Espinosa Leija, Armando
Hernández, Guadalupe
Cruz, Sandra
Bernès, Sylvain
Gutiérrez, René
author_facet Espinosa Leija, Armando
Hernández, Guadalupe
Cruz, Sandra
Bernès, Sylvain
Gutiérrez, René
author_sort Espinosa Leija, Armando
collection PubMed
description In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral groups including imine functionalities, with the common E configuration. The dihedral angle between the central benzene ring and the terminal naphthalene ring is 45.42 (9)° and that between the two naphthalene rings is 89.16 (8)°. The conformation of the Schiff base allows solvent mol­ecules to fill the voids in the crystal, affording a stable 1:1 solvate, but the solvent inter­acts poorly with the Schiff base, as reflected by its rather high displacement parameters.
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spelling pubmed-29698042010-12-30 1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate Espinosa Leija, Armando Hernández, Guadalupe Cruz, Sandra Bernès, Sylvain Gutiérrez, René Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral groups including imine functionalities, with the common E configuration. The dihedral angle between the central benzene ring and the terminal naphthalene ring is 45.42 (9)° and that between the two naphthalene rings is 89.16 (8)°. The conformation of the Schiff base allows solvent mol­ecules to fill the voids in the crystal, affording a stable 1:1 solvate, but the solvent inter­acts poorly with the Schiff base, as reflected by its rather high displacement parameters. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969804/ /pubmed/21583173 http://dx.doi.org/10.1107/S1600536809017528 Text en © Espinosa Leija et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Espinosa Leija, Armando
Hernández, Guadalupe
Cruz, Sandra
Bernès, Sylvain
Gutiérrez, René
1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
title 1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
title_full 1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
title_fullStr 1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
title_full_unstemmed 1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
title_short 1,3-Bis{(+)-(S)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
title_sort 1,3-bis{(+)-(s)-[1-(1-naphth­yl)eth­yl]imino­meth­yl}benzene dichloro­methane solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969804/
https://www.ncbi.nlm.nih.gov/pubmed/21583173
http://dx.doi.org/10.1107/S1600536809017528
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