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1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate
In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral gr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969804/ https://www.ncbi.nlm.nih.gov/pubmed/21583173 http://dx.doi.org/10.1107/S1600536809017528 |
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author | Espinosa Leija, Armando Hernández, Guadalupe Cruz, Sandra Bernès, Sylvain Gutiérrez, René |
author_facet | Espinosa Leija, Armando Hernández, Guadalupe Cruz, Sandra Bernès, Sylvain Gutiérrez, René |
author_sort | Espinosa Leija, Armando |
collection | PubMed |
description | In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral groups including imine functionalities, with the common E configuration. The dihedral angle between the central benzene ring and the terminal naphthalene ring is 45.42 (9)° and that between the two naphthalene rings is 89.16 (8)°. The conformation of the Schiff base allows solvent molecules to fill the voids in the crystal, affording a stable 1:1 solvate, but the solvent interacts poorly with the Schiff base, as reflected by its rather high displacement parameters. |
format | Text |
id | pubmed-2969804 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29698042010-12-30 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate Espinosa Leija, Armando Hernández, Guadalupe Cruz, Sandra Bernès, Sylvain Gutiérrez, René Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral groups including imine functionalities, with the common E configuration. The dihedral angle between the central benzene ring and the terminal naphthalene ring is 45.42 (9)° and that between the two naphthalene rings is 89.16 (8)°. The conformation of the Schiff base allows solvent molecules to fill the voids in the crystal, affording a stable 1:1 solvate, but the solvent interacts poorly with the Schiff base, as reflected by its rather high displacement parameters. International Union of Crystallography 2009-05-20 /pmc/articles/PMC2969804/ /pubmed/21583173 http://dx.doi.org/10.1107/S1600536809017528 Text en © Espinosa Leija et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Espinosa Leija, Armando Hernández, Guadalupe Cruz, Sandra Bernès, Sylvain Gutiérrez, René 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
title | 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
title_full | 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
title_fullStr | 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
title_full_unstemmed | 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
title_short | 1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
title_sort | 1,3-bis{(+)-(s)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969804/ https://www.ncbi.nlm.nih.gov/pubmed/21583173 http://dx.doi.org/10.1107/S1600536809017528 |
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