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4-Benzyl-6-p-tolylpyridazin-3(2H)-one
The title compound, C(18)H(16)N(2)O, is a new dihydropyridazin-3(2H)-one derivative synthesized in one step by condensation of α-benzylidene-γ-tolylbutenolide with hydrazine. The molecule is not planar; the tolyl and pyridazine rings are twisted with respect to each other making a dihedral angle...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969805/ https://www.ncbi.nlm.nih.gov/pubmed/21583202 http://dx.doi.org/10.1107/S1600536809018376 |
Sumario: | The title compound, C(18)H(16)N(2)O, is a new dihydropyridazin-3(2H)-one derivative synthesized in one step by condensation of α-benzylidene-γ-tolylbutenolide with hydrazine. The molecule is not planar; the tolyl and pyridazine rings are twisted with respect to each other making a dihedral angle of 27.35 (9)° and the benzyl ring is nearly perpendicular to the pyridazine ring with a dihedral angle of 85.24 (5)°. In the crystal structure, inversion dimers arise, being linked by pairs of N—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds and weak offset π–π stacking stabilize the packing. The π–π stacking occurs between the pyridazine rings of symmetry-related molecules, with a centroid–centroid distance of 3.748 Å, an interplanar distance of 3.605 Å and a slippage of 1.024 Å. |
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