Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]

In the title complex, [La(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by eight O atoms from two 2-oxido­pyridinium-3-carboxyl­ate ligands, two oxalate ligands and two water mol­ecules in a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups link adja...

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Detalles Bibliográficos
Autores principales: Hu, Zhen, Zhu, Zhi-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969809/
https://www.ncbi.nlm.nih.gov/pubmed/21583041
http://dx.doi.org/10.1107/S1600536809018194
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author Hu, Zhen
Zhu, Zhi-Bo
author_facet Hu, Zhen
Zhu, Zhi-Bo
author_sort Hu, Zhen
collection PubMed
description In the title complex, [La(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by eight O atoms from two 2-oxido­pyridinium-3-carboxyl­ate ligands, two oxalate ligands and two water mol­ecules in a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups link adjacent La(III) ions, forming two-dimensional layers that are further linked by N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29698092010-12-30 Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)] Hu, Zhen Zhu, Zhi-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by eight O atoms from two 2-oxido­pyridinium-3-carboxyl­ate ligands, two oxalate ligands and two water mol­ecules in a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups link adjacent La(III) ions, forming two-dimensional layers that are further linked by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969809/ /pubmed/21583041 http://dx.doi.org/10.1107/S1600536809018194 Text en © Hu and Zhu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Zhen
Zhu, Zhi-Bo
Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]
title Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]
title_full Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]
title_fullStr Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]
title_full_unstemmed Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]
title_short Poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(III)]
title_sort poly[diaqua­(μ-oxalato)(μ-2-oxidopyridinium-3-carboxyl­ato)lanthanum(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969809/
https://www.ncbi.nlm.nih.gov/pubmed/21583041
http://dx.doi.org/10.1107/S1600536809018194
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