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Bis(di-2-pyridylmethanediol-κ(3) N,O,N′)nickel(II) dinitrate
The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethanediol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octahedral. The gem...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969811/ https://www.ncbi.nlm.nih.gov/pubmed/21583038 http://dx.doi.org/10.1107/S1600536809018728 |
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author | Yu, Seung Man Song, Young Joo Kim, Kang Chul Kim, Cheal Kim, Youngmee |
author_facet | Yu, Seung Man Song, Young Joo Kim, Kang Chul Kim, Cheal Kim, Youngmee |
author_sort | Yu, Seung Man |
collection | PubMed |
description | The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethanediol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octahedral. The gem-diol (2-py)(2)C(OH)(2) ligand adopts the coordination mode η(1):η(1):η(1). The Ni—N and Ni—O bond lengths are typical for high-spin Ni(II) in an octahedral environment [Ni—N = 2.094 (2) and 2.124 (3) Å, and Ni—O = 2.108 (3) Å]. One of the hydroxy H atoms is split over two positions which both interact with the nitrate anion. The occurence of different O—H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane. |
format | Text |
id | pubmed-2969811 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29698112010-12-30 Bis(di-2-pyridylmethanediol-κ(3) N,O,N′)nickel(II) dinitrate Yu, Seung Man Song, Young Joo Kim, Kang Chul Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethanediol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octahedral. The gem-diol (2-py)(2)C(OH)(2) ligand adopts the coordination mode η(1):η(1):η(1). The Ni—N and Ni—O bond lengths are typical for high-spin Ni(II) in an octahedral environment [Ni—N = 2.094 (2) and 2.124 (3) Å, and Ni—O = 2.108 (3) Å]. One of the hydroxy H atoms is split over two positions which both interact with the nitrate anion. The occurence of different O—H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969811/ /pubmed/21583038 http://dx.doi.org/10.1107/S1600536809018728 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yu, Seung Man Song, Young Joo Kim, Kang Chul Kim, Cheal Kim, Youngmee Bis(di-2-pyridylmethanediol-κ(3) N,O,N′)nickel(II) dinitrate |
title | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)nickel(II) dinitrate |
title_full | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)nickel(II) dinitrate |
title_fullStr | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)nickel(II) dinitrate |
title_full_unstemmed | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)nickel(II) dinitrate |
title_short | Bis(di-2-pyridylmethanediol-κ(3)
N,O,N′)nickel(II) dinitrate |
title_sort | bis(di-2-pyridylmethanediol-κ(3)
n,o,n′)nickel(ii) dinitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969811/ https://www.ncbi.nlm.nih.gov/pubmed/21583038 http://dx.doi.org/10.1107/S1600536809018728 |
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