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Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate

The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethane­diol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octa­hedral. The gem...

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Detalles Bibliográficos
Autores principales: Yu, Seung Man, Song, Young Joo, Kim, Kang Chul, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969811/
https://www.ncbi.nlm.nih.gov/pubmed/21583038
http://dx.doi.org/10.1107/S1600536809018728
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author Yu, Seung Man
Song, Young Joo
Kim, Kang Chul
Kim, Cheal
Kim, Youngmee
author_facet Yu, Seung Man
Song, Young Joo
Kim, Kang Chul
Kim, Cheal
Kim, Youngmee
author_sort Yu, Seung Man
collection PubMed
description The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethane­diol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octa­hedral. The gem-diol (2-py)(2)C(OH)(2) ligand adopts the coordination mode η(1):η(1):η(1). The Ni—N and Ni—O bond lengths are typical for high-spin Ni(II) in an octa­hedral environment [Ni—N = 2.094 (2) and 2.124 (3) Å, and Ni—O = 2.108 (3) Å]. One of the hydr­oxy H atoms is split over two positions which both inter­act with the nitrate anion. The occurence of different O—H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.
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spelling pubmed-29698112010-12-30 Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate Yu, Seung Man Song, Young Joo Kim, Kang Chul Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethane­diol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octa­hedral. The gem-diol (2-py)(2)C(OH)(2) ligand adopts the coordination mode η(1):η(1):η(1). The Ni—N and Ni—O bond lengths are typical for high-spin Ni(II) in an octa­hedral environment [Ni—N = 2.094 (2) and 2.124 (3) Å, and Ni—O = 2.108 (3) Å]. One of the hydr­oxy H atoms is split over two positions which both inter­act with the nitrate anion. The occurence of different O—H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969811/ /pubmed/21583038 http://dx.doi.org/10.1107/S1600536809018728 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Seung Man
Song, Young Joo
Kim, Kang Chul
Kim, Cheal
Kim, Youngmee
Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate
title Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate
title_full Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate
title_fullStr Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate
title_full_unstemmed Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate
title_short Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)nickel(II) dinitrate
title_sort bis(di-2-pyridylmethane­diol-κ(3) n,o,n′)nickel(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969811/
https://www.ncbi.nlm.nih.gov/pubmed/21583038
http://dx.doi.org/10.1107/S1600536809018728
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