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trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)

In the title compound, [Cu(C(6)H(5)N(2)O(4))(2)], the copper(II) atom lies on an inversion centre and is in an N(2)O(2) four-coordinate environment with a nearly regular square-planar geometry. An extended network of intra­molecular O—H⋯O and inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stabil­ize...

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Detalles Bibliográficos
Autores principales: Guo, Xin, Li, Yi Liang, Wang, Ju Xian, Wang, Yu Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969817/
https://www.ncbi.nlm.nih.gov/pubmed/21583005
http://dx.doi.org/10.1107/S1600536809016791
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author Guo, Xin
Li, Yi Liang
Wang, Ju Xian
Wang, Yu Cheng
author_facet Guo, Xin
Li, Yi Liang
Wang, Ju Xian
Wang, Yu Cheng
author_sort Guo, Xin
collection PubMed
description In the title compound, [Cu(C(6)H(5)N(2)O(4))(2)], the copper(II) atom lies on an inversion centre and is in an N(2)O(2) four-coordinate environment with a nearly regular square-planar geometry. An extended network of intra­molecular O—H⋯O and inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stabil­izes the crystal structure.
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spelling pubmed-29698172010-12-30 trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II) Guo, Xin Li, Yi Liang Wang, Ju Xian Wang, Yu Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(5)N(2)O(4))(2)], the copper(II) atom lies on an inversion centre and is in an N(2)O(2) four-coordinate environment with a nearly regular square-planar geometry. An extended network of intra­molecular O—H⋯O and inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stabil­izes the crystal structure. International Union of Crystallography 2009-05-14 /pmc/articles/PMC2969817/ /pubmed/21583005 http://dx.doi.org/10.1107/S1600536809016791 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Xin
Li, Yi Liang
Wang, Ju Xian
Wang, Yu Cheng
trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)
title trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)
title_full trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)
title_fullStr trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)
title_full_unstemmed trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)
title_short trans-Bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))copper(II)
title_sort trans-bis(5-carb­oxy-2-methyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969817/
https://www.ncbi.nlm.nih.gov/pubmed/21583005
http://dx.doi.org/10.1107/S1600536809016791
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