Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate

In the title mononuclear complex, [Ni(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Ni(II) atom is six-coordinated by one N atom from a 1H-benzimidazole-5,6-dicarboxyl­ate ligand and by five O atoms from five water mol­ecules and displays a distorted octa­hedral geometry. Inter­molecular O—H⋯O hydrogen-b...

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Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Wang, Hao, Qin, Pei-Wen, Li, Shi-Jie, Hu, Shi-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969820/
https://www.ncbi.nlm.nih.gov/pubmed/21583033
http://dx.doi.org/10.1107/S1600536809018704
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author Song, Wen-Dong
Wang, Hao
Qin, Pei-Wen
Li, Shi-Jie
Hu, Shi-Wei
author_facet Song, Wen-Dong
Wang, Hao
Qin, Pei-Wen
Li, Shi-Jie
Hu, Shi-Wei
author_sort Song, Wen-Dong
collection PubMed
description In the title mononuclear complex, [Ni(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Ni(II) atom is six-coordinated by one N atom from a 1H-benzimidazole-5,6-dicarboxyl­ate ligand and by five O atoms from five water mol­ecules and displays a distorted octa­hedral geometry. Inter­molecular O—H⋯O hydrogen-bonding inter­actions among the coordinated water mol­ecules, solvent water mol­ecules and carboxyl O atoms of the organic ligand and additional N—H⋯O hydrogen bonding lead to the formation of a three-dimensional supra­molecular network.
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spelling pubmed-29698202010-12-30 Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate Song, Wen-Dong Wang, Hao Qin, Pei-Wen Li, Shi-Jie Hu, Shi-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ni(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Ni(II) atom is six-coordinated by one N atom from a 1H-benzimidazole-5,6-dicarboxyl­ate ligand and by five O atoms from five water mol­ecules and displays a distorted octa­hedral geometry. Inter­molecular O—H⋯O hydrogen-bonding inter­actions among the coordinated water mol­ecules, solvent water mol­ecules and carboxyl O atoms of the organic ligand and additional N—H⋯O hydrogen bonding lead to the formation of a three-dimensional supra­molecular network. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969820/ /pubmed/21583033 http://dx.doi.org/10.1107/S1600536809018704 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Wang, Hao
Qin, Pei-Wen
Li, Shi-Jie
Hu, Shi-Wei
Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate
title Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate
title_full Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate
title_fullStr Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate
title_full_unstemmed Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate
title_short Penta­aqua­(1H-benzimidazole-5,6-dicarboxyl­ato-κN (3))nickel(II) penta­hydrate
title_sort penta­aqua­(1h-benzimidazole-5,6-dicarboxyl­ato-κn (3))nickel(ii) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969820/
https://www.ncbi.nlm.nih.gov/pubmed/21583033
http://dx.doi.org/10.1107/S1600536809018704
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