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Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate
In the title compound, [Fe(C(5)H(5))(C(21)H(20)NO(5))], the pyrrolidine and cyclopentanone rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclopentanone ring, making a dihedral angle of 81.91 (6)°. The molecular conformation is stabilized by an intramol...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969822/ https://www.ncbi.nlm.nih.gov/pubmed/21583045 http://dx.doi.org/10.1107/S1600536809018583 |
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| author | Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Kathiravan, S. Raghunathan, R. |
| author_facet | Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Kathiravan, S. Raghunathan, R. |
| author_sort | Kamala, E. Theboral Sugi |
| collection | PubMed |
| description | In the title compound, [Fe(C(5)H(5))(C(21)H(20)NO(5))], the pyrrolidine and cyclopentanone rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclopentanone ring, making a dihedral angle of 81.91 (6)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond and C—H⋯O interactions. The crystal structure is stabilized by intermolecular C—H⋯O interactions. |
| format | Text |
| id | pubmed-2969822 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29698222010-12-30 Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Kathiravan, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(21)H(20)NO(5))], the pyrrolidine and cyclopentanone rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclopentanone ring, making a dihedral angle of 81.91 (6)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond and C—H⋯O interactions. The crystal structure is stabilized by intermolecular C—H⋯O interactions. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969822/ /pubmed/21583045 http://dx.doi.org/10.1107/S1600536809018583 Text en © Kamala et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Kathiravan, S. Raghunathan, R. Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| title | Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| title_full | Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| title_fullStr | Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| title_full_unstemmed | Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| title_short | Methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1H-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| title_sort | methyl 5-ferrocenyl-5a-hydroxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexahydro-1h-indeno[1,2:2′,3′]furo[3′,4′-b]pyrrole-3a-carboxylate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969822/ https://www.ncbi.nlm.nih.gov/pubmed/21583045 http://dx.doi.org/10.1107/S1600536809018583 |
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