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Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3) O (1),O (1′):O (2);κ(3) O (2):O (1),O (1′)-bis[aqua(1,10-phenanthroline-κ(2) N,N′)nickel(II)]
The title compound, [Ni(2)(C(9)H(6)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], is isostructural with the Zn(II) analogue. Each Ni(II) atom is coordinated in a distorted octahedral geometry by three O atoms from two homophthalate anions, one aqua O atom and two 1,10-phenanthroline N atoms. The two Ni(II)...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969824/ https://www.ncbi.nlm.nih.gov/pubmed/21583040 http://dx.doi.org/10.1107/S1600536809018339 |
| _version_ | 1782190271334711296 |
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| author | Li, Feng Zeng, Huifang Yan, Zhaowei Li, Taohai |
| author_facet | Li, Feng Zeng, Huifang Yan, Zhaowei Li, Taohai |
| author_sort | Li, Feng |
| collection | PubMed |
| description | The title compound, [Ni(2)(C(9)H(6)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], is isostructural with the Zn(II) analogue. Each Ni(II) atom is coordinated in a distorted octahedral geometry by three O atoms from two homophthalate anions, one aqua O atom and two 1,10-phenanthroline N atoms. The two Ni(II) atoms are linked by two bridging homophthalate dianions into a centrosymmetric dinuclear unit. The dinuclear units are linked into one-dimensional ladder-like chains along [100] by O—H⋯O hydrogen bonds between the coordinated water molecules and one of the O atoms of the carboxylatomethyl group. |
| format | Text |
| id | pubmed-2969824 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29698242010-12-30 Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3) O (1),O (1′):O (2);κ(3) O (2):O (1),O (1′)-bis[aqua(1,10-phenanthroline-κ(2) N,N′)nickel(II)] Li, Feng Zeng, Huifang Yan, Zhaowei Li, Taohai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(2)(C(9)H(6)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], is isostructural with the Zn(II) analogue. Each Ni(II) atom is coordinated in a distorted octahedral geometry by three O atoms from two homophthalate anions, one aqua O atom and two 1,10-phenanthroline N atoms. The two Ni(II) atoms are linked by two bridging homophthalate dianions into a centrosymmetric dinuclear unit. The dinuclear units are linked into one-dimensional ladder-like chains along [100] by O—H⋯O hydrogen bonds between the coordinated water molecules and one of the O atoms of the carboxylatomethyl group. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969824/ /pubmed/21583040 http://dx.doi.org/10.1107/S1600536809018339 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Feng Zeng, Huifang Yan, Zhaowei Li, Taohai Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3) O (1),O (1′):O (2);κ(3) O (2):O (1),O (1′)-bis[aqua(1,10-phenanthroline-κ(2) N,N′)nickel(II)] |
| title | Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3)
O
(1),O
(1′):O
(2);κ(3)
O
(2):O
(1),O
(1′)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)] |
| title_full | Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3)
O
(1),O
(1′):O
(2);κ(3)
O
(2):O
(1),O
(1′)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)] |
| title_fullStr | Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3)
O
(1),O
(1′):O
(2);κ(3)
O
(2):O
(1),O
(1′)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)] |
| title_full_unstemmed | Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3)
O
(1),O
(1′):O
(2);κ(3)
O
(2):O
(1),O
(1′)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)] |
| title_short | Bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3)
O
(1),O
(1′):O
(2);κ(3)
O
(2):O
(1),O
(1′)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)nickel(II)] |
| title_sort | bis[μ-2-(2-carboxylatophenyl)acetato]-κ(3)
o
(1),o
(1′):o
(2);κ(3)
o
(2):o
(1),o
(1′)-bis[aqua(1,10-phenanthroline-κ(2)
n,n′)nickel(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969824/ https://www.ncbi.nlm.nih.gov/pubmed/21583040 http://dx.doi.org/10.1107/S1600536809018339 |
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