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Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]

In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal–prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom...

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Detalles Bibliográficos
Autores principales: Wen, Yan-Mei, Feng, Tian-Jun, He, Li-Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969826/
https://www.ncbi.nlm.nih.gov/pubmed/21583037
http://dx.doi.org/10.1107/S160053680901842X
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author Wen, Yan-Mei
Feng, Tian-Jun
He, Li-Xin
author_facet Wen, Yan-Mei
Feng, Tian-Jun
He, Li-Xin
author_sort Wen, Yan-Mei
collection PubMed
description In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal–prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom from either a nitrate ion or a water mol­ecule, both of which are half-occupied over the same site. One Ag(I) atom has a Y-shaped geometry defined by one N atom from one IN ligand, one O atom from another IN ligand and one O atom from an oxalate ligand. The other Ag(I) atom is coordinated by two IN ligands and one O atom from an oxalate ligand. One of the IN ligands is disordered over an inversion center and forms a bridge between two centrosymmetric Ag(I) ions. Due to the disorder, this IN ligand coordinates to the Ag atom through either the pyridyl N or the carboxyl­ate O atoms. The IN and oxalate ligands link the Er and Ag atoms into a three-dimensional coordination framework. O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure.
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spelling pubmed-29698262010-12-30 Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate] Wen, Yan-Mei Feng, Tian-Jun He, Li-Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal–prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom from either a nitrate ion or a water mol­ecule, both of which are half-occupied over the same site. One Ag(I) atom has a Y-shaped geometry defined by one N atom from one IN ligand, one O atom from another IN ligand and one O atom from an oxalate ligand. The other Ag(I) atom is coordinated by two IN ligands and one O atom from an oxalate ligand. One of the IN ligands is disordered over an inversion center and forms a bridge between two centrosymmetric Ag(I) ions. Due to the disorder, this IN ligand coordinates to the Ag atom through either the pyridyl N or the carboxyl­ate O atoms. The IN and oxalate ligands link the Er and Ag atoms into a three-dimensional coordination framework. O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969826/ /pubmed/21583037 http://dx.doi.org/10.1107/S160053680901842X Text en © Wen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Yan-Mei
Feng, Tian-Jun
He, Li-Xin
Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]
title Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]
title_full Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]
title_fullStr Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]
title_full_unstemmed Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]
title_short Poly[[aqua­bis(μ(3)-isonicotinato-κ(3) O:O′:N)tris­(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis­(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetra­silver(I)] tetra­hydrate]
title_sort poly[[aqua­bis(μ(3)-isonicotinato-κ(3) o:o′:n)tris­(μ(2)-isonicotinato-κ(3) o,o′:n)(nitrato-κo)bis­(μ(4)-oxalato-κ(6) o (1),o (2):o (2):o (1′),o (2′):o (1′))dierbium(iii)tetra­silver(i)] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969826/
https://www.ncbi.nlm.nih.gov/pubmed/21583037
http://dx.doi.org/10.1107/S160053680901842X
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