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Poly[[aquabis(μ(3)-isonicotinato-κ(3) O:O′:N)tris(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetrasilver(I)] tetrahydrate]
In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal–prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969826/ https://www.ncbi.nlm.nih.gov/pubmed/21583037 http://dx.doi.org/10.1107/S160053680901842X |
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author | Wen, Yan-Mei Feng, Tian-Jun He, Li-Xin |
author_facet | Wen, Yan-Mei Feng, Tian-Jun He, Li-Xin |
author_sort | Wen, Yan-Mei |
collection | PubMed |
description | In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal–prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom from either a nitrate ion or a water molecule, both of which are half-occupied over the same site. One Ag(I) atom has a Y-shaped geometry defined by one N atom from one IN ligand, one O atom from another IN ligand and one O atom from an oxalate ligand. The other Ag(I) atom is coordinated by two IN ligands and one O atom from an oxalate ligand. One of the IN ligands is disordered over an inversion center and forms a bridge between two centrosymmetric Ag(I) ions. Due to the disorder, this IN ligand coordinates to the Ag atom through either the pyridyl N or the carboxylate O atoms. The IN and oxalate ligands link the Er and Ag atoms into a three-dimensional coordination framework. O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure. |
format | Text |
id | pubmed-2969826 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29698262010-12-30 Poly[[aquabis(μ(3)-isonicotinato-κ(3) O:O′:N)tris(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetrasilver(I)] tetrahydrate] Wen, Yan-Mei Feng, Tian-Jun He, Li-Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal–prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom from either a nitrate ion or a water molecule, both of which are half-occupied over the same site. One Ag(I) atom has a Y-shaped geometry defined by one N atom from one IN ligand, one O atom from another IN ligand and one O atom from an oxalate ligand. The other Ag(I) atom is coordinated by two IN ligands and one O atom from an oxalate ligand. One of the IN ligands is disordered over an inversion center and forms a bridge between two centrosymmetric Ag(I) ions. Due to the disorder, this IN ligand coordinates to the Ag atom through either the pyridyl N or the carboxylate O atoms. The IN and oxalate ligands link the Er and Ag atoms into a three-dimensional coordination framework. O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2009-05-23 /pmc/articles/PMC2969826/ /pubmed/21583037 http://dx.doi.org/10.1107/S160053680901842X Text en © Wen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wen, Yan-Mei Feng, Tian-Jun He, Li-Xin Poly[[aquabis(μ(3)-isonicotinato-κ(3) O:O′:N)tris(μ(2)-isonicotinato-κ(3) O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6) O (1),O (2):O (2):O (1′),O (2′):O (1′))dierbium(III)tetrasilver(I)] tetrahydrate] |
title | Poly[[aquabis(μ(3)-isonicotinato-κ(3)
O:O′:N)tris(μ(2)-isonicotinato-κ(3)
O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6)
O
(1),O
(2):O
(2):O
(1′),O
(2′):O
(1′))dierbium(III)tetrasilver(I)] tetrahydrate] |
title_full | Poly[[aquabis(μ(3)-isonicotinato-κ(3)
O:O′:N)tris(μ(2)-isonicotinato-κ(3)
O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6)
O
(1),O
(2):O
(2):O
(1′),O
(2′):O
(1′))dierbium(III)tetrasilver(I)] tetrahydrate] |
title_fullStr | Poly[[aquabis(μ(3)-isonicotinato-κ(3)
O:O′:N)tris(μ(2)-isonicotinato-κ(3)
O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6)
O
(1),O
(2):O
(2):O
(1′),O
(2′):O
(1′))dierbium(III)tetrasilver(I)] tetrahydrate] |
title_full_unstemmed | Poly[[aquabis(μ(3)-isonicotinato-κ(3)
O:O′:N)tris(μ(2)-isonicotinato-κ(3)
O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6)
O
(1),O
(2):O
(2):O
(1′),O
(2′):O
(1′))dierbium(III)tetrasilver(I)] tetrahydrate] |
title_short | Poly[[aquabis(μ(3)-isonicotinato-κ(3)
O:O′:N)tris(μ(2)-isonicotinato-κ(3)
O,O′:N)(nitrato-κO)bis(μ(4)-oxalato-κ(6)
O
(1),O
(2):O
(2):O
(1′),O
(2′):O
(1′))dierbium(III)tetrasilver(I)] tetrahydrate] |
title_sort | poly[[aquabis(μ(3)-isonicotinato-κ(3)
o:o′:n)tris(μ(2)-isonicotinato-κ(3)
o,o′:n)(nitrato-κo)bis(μ(4)-oxalato-κ(6)
o
(1),o
(2):o
(2):o
(1′),o
(2′):o
(1′))dierbium(iii)tetrasilver(i)] tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969826/ https://www.ncbi.nlm.nih.gov/pubmed/21583037 http://dx.doi.org/10.1107/S160053680901842X |
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