Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)

The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol­ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa­hedral coordination environment. O...

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Detalles Bibliográficos
Autores principales: Tan, Chui Lian, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969832/
https://www.ncbi.nlm.nih.gov/pubmed/21583050
http://dx.doi.org/10.1107/S1600536809019242
Descripción
Sumario:The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol­ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa­hedral coordination environment. One chloro­benzyl substituent is disordered in each mol­ecule in 0.5:0.5 and 0.778 (2):0.222 (2) ratios.

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