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Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)

The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol­ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa­hedral coordination environment. O...

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Detalles Bibliográficos
Autores principales: Tan, Chui Lian, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969832/
https://www.ncbi.nlm.nih.gov/pubmed/21583050
http://dx.doi.org/10.1107/S1600536809019242
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author Tan, Chui Lian
Lo, Kong Mun
Ng, Seik Weng
author_facet Tan, Chui Lian
Lo, Kong Mun
Ng, Seik Weng
author_sort Tan, Chui Lian
collection PubMed
description The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol­ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa­hedral coordination environment. One chloro­benzyl substituent is disordered in each mol­ecule in 0.5:0.5 and 0.778 (2):0.222 (2) ratios.
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spelling pubmed-29698322010-12-30 Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV) Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol­ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa­hedral coordination environment. One chloro­benzyl substituent is disordered in each mol­ecule in 0.5:0.5 and 0.778 (2):0.222 (2) ratios. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969832/ /pubmed/21583050 http://dx.doi.org/10.1107/S1600536809019242 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Chui Lian
Lo, Kong Mun
Ng, Seik Weng
Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
title Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
title_full Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
title_fullStr Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
title_full_unstemmed Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
title_short Dichloridobis(2-chloro­benzyl-κC)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
title_sort dichloridobis(2-chloro­benzyl-κc)[5,6-diphenyl-3-(2-pyrid­yl)-1,2,4-triazine-κ(2) n (2),n (3)]tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969832/
https://www.ncbi.nlm.nih.gov/pubmed/21583050
http://dx.doi.org/10.1107/S1600536809019242
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