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Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV)
The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent molecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octahedral coordination environment. O...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969832/ https://www.ncbi.nlm.nih.gov/pubmed/21583050 http://dx.doi.org/10.1107/S1600536809019242 |
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author | Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng |
author_facet | Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng |
author_sort | Tan, Chui Lian |
collection | PubMed |
description | The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent molecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octahedral coordination environment. One chlorobenzyl substituent is disordered in each molecule in 0.5:0.5 and 0.778 (2):0.222 (2) ratios. |
format | Text |
id | pubmed-2969832 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29698322010-12-30 Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV) Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent molecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octahedral coordination environment. One chlorobenzyl substituent is disordered in each molecule in 0.5:0.5 and 0.778 (2):0.222 (2) ratios. International Union of Crystallography 2009-05-29 /pmc/articles/PMC2969832/ /pubmed/21583050 http://dx.doi.org/10.1107/S1600536809019242 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2) N (2),N (3)]tin(IV) |
title | Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]tin(IV) |
title_full | Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]tin(IV) |
title_fullStr | Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]tin(IV) |
title_full_unstemmed | Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]tin(IV) |
title_short | Dichloridobis(2-chlorobenzyl-κC)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]tin(IV) |
title_sort | dichloridobis(2-chlorobenzyl-κc)[5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine-κ(2)
n
(2),n
(3)]tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969832/ https://www.ncbi.nlm.nih.gov/pubmed/21583050 http://dx.doi.org/10.1107/S1600536809019242 |
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