Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer

The title compound catena-poly[aqua­sodium-μ(2)-aqua-μ(3)-2-nitro­cinnamato], [Na(C(9)H(6)NO(4))(H(2)O)(2)](n), the sodium salt of trans-2-nitro­cinnamic acid, is a one-dimensional coordination polymer based on six-coordinate octa­hedral NaO(6) centres, comprising three facially related monodentate...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969855/
https://www.ncbi.nlm.nih.gov/pubmed/21577409
http://dx.doi.org/10.1107/S1600536809030402
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description The title compound catena-poly[aqua­sodium-μ(2)-aqua-μ(3)-2-nitro­cinnamato], [Na(C(9)H(6)NO(4))(H(2)O)(2)](n), the sodium salt of trans-2-nitro­cinnamic acid, is a one-dimensional coordination polymer based on six-coordinate octa­hedral NaO(6) centres, comprising three facially related monodentate carboxyl­ate O-atom donors from separate ligands (all bridging) [Na—O = 2.4370 (13)–2.5046 (13) Å], and three water mol­ecules (two bridging and one monodentate) [Na—O = 2.3782 (13)–2.4404 (17) Å]. The structure is also stabilized by intra-chain water–carboxyl­ate and water–nitro O—H⋯O hydrogen bonds.
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spelling pubmed-29698552010-12-30 Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound catena-poly[aqua­sodium-μ(2)-aqua-μ(3)-2-nitro­cinnamato], [Na(C(9)H(6)NO(4))(H(2)O)(2)](n), the sodium salt of trans-2-nitro­cinnamic acid, is a one-dimensional coordination polymer based on six-coordinate octa­hedral NaO(6) centres, comprising three facially related monodentate carboxyl­ate O-atom donors from separate ligands (all bridging) [Na—O = 2.4370 (13)–2.5046 (13) Å], and three water mol­ecules (two bridging and one monodentate) [Na—O = 2.3782 (13)–2.4404 (17) Å]. The structure is also stabilized by intra-chain water–carboxyl­ate and water–nitro O—H⋯O hydrogen bonds. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969855/ /pubmed/21577409 http://dx.doi.org/10.1107/S1600536809030402 Text en © Smith and Wermuth 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Smith, Graham
Wermuth, Urs D.
Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
title Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
title_full Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
title_fullStr Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
title_full_unstemmed Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
title_short Sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
title_sort sodium 2-nitro­cinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969855/
https://www.ncbi.nlm.nih.gov/pubmed/21577409
http://dx.doi.org/10.1107/S1600536809030402
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AT wermuthursd sodium2nitrocinnamatedihydrateaonedimensionalhydrogenbondedcoordinationpolymer

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